Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has
brought new opportunities in sophisticated macromolecular synthesis. However, the …

The incorporation of heteroatom-containing weak bonds along polymer backbones has
become a popular tool to accelerate degradation. Many methods have already been …

Nature shows us that complex molecular architectures lead to unique material properties,
and these observations have driven polymer scientists to synthesize complex architectures …

Light has emerged as a prominent stimulus to both generate and manipulate polymeric
materials across multiple length scales. Compared with other external stimuli, light-mediated …

Chirality, an inherent characteristic observed throughout nature, plays a pivotal role across a
wide range of scales, from subatomic to galactic, and holds significance in myriad scientific …

Controlled radical copolymerizations present attractive avenues to obtain polymers with
complicated compositions and sequences. In this work, we report the development of a …

Organocatalyzed reversible‐deactivation radical polymerizations (RDRPs) are attractive for
many applications. Here, we developed photoredox‐mediated RDRP by activating (hetero) …

Visible light-regulated metal-free polymerizations have attracted considerable attention for
macromolecular syntheses in recent years. However, few organic photocatalysts show high …

Polymerization catalysts that activate in response to specific chemical triggers offer spatial
and temporal control over polymer synthesis, facilitating the development of responsive …

The incorporation of main group elements into polymers allows for the generation of new
functional materials with hitherto-unattainable physical and chemical properties through the …