Structural, magnetic, and spectroscopic data on a Mn3+ spin-crossover complex with Schiff
base ligand 4-OMe-Sal2323, isolated in crystal lattices with five different counteranions, are …

Considering the overwhelming importance and involvement of iron in numerous biocatalytic
processes, the scarceness of synthetic iron complexes as water oxidation catalysts (WOCs) …

We report an experimental observation of 31P NMR resonances shifted by over 10 000 ppm
(meaning percent range, and a new record for solutions), and similar 1H chemical shifts, in …

A mono-DMSO cobalt meso-CF3 corrole, formulated as (CF3) 3CorCo (DMSO), where (CF3)
3Cor is the trianion of 5, 10, 15-tris (trifluoromethyl) corrole, was synthesized and …

Complex assembly preferences and resultant spin state choice and Jahn-Teller distortion
mode in twelve Mn (III) complexes of varying nuclearity with Schiff base chelate ligands of …

Starting from its discovery, electron paramagnetic resonance (EPR) is a constantly
developing technique following technological advances in generation and detection of …

Herein, we combine for the first time SQUID magnetometry, cw-EPR, THz-EPR, and
paramagnetic NMR spectroscopies to study the magnetic properties of a high-spin cobalt (II) …

A three-component reaction of antiaromatic meso-mesityl-3-nitronorcorrolatonickel (II) 1-
NO2 with dialkyl acetylenedicarboxylate and PBu3 yields aromatic zwitterionic corrole nickel …

Manganese complexes supported by macrocyclic tetrapyrrole ligands represent an
important platform for nitrene transfer catalysis and have been applied to both C− H …

Extensive DFT calculations with several exchange–correlation functionals indicate that
molybdenum-dichlorido Viking helmet corroles are noninnocent with significant MoIV …