Hypervalent organoantimony and-bismuth compounds with pendant arm ligands
CI Raţ, C Silvestru, HJ Breunig - Coordination Chemistry Reviews, 2013 - Elsevier
Recent developments in chemistry of hypervalent organoantimony and-bismuth complexes
with bidentate (C, E)-and tridentate (E, C, E)-and (C, E, C)-ligands are reviewed. The ligands …
with bidentate (C, E)-and tridentate (E, C, E)-and (C, E, C)-ligands are reviewed. The ligands …
Organobismuth reagents: synthesis, properties and applications in organic synthesis
A Gagnon, J Dansereau, A Le Roch - Synthesis, 2017 - thieme-connect.com
Organobismuth compounds are organometallic reagents that contain a C–Bi bond. These
species, which are easily accessed from inexpensive and low-toxicity inorganic bismuth …
species, which are easily accessed from inexpensive and low-toxicity inorganic bismuth …
Periodicity in Structure, Bonding, and Reactivity for p‐Block Complexes of a Geometry Constraining Triamide Ligand
KM Marczenko, JA Zurakowski… - … A European Journal, 2019 - Wiley Online Library
The use of pincer ligands to access non‐VSEPR geometries at main‐group centers is an
emerging strategy for eliciting new stoichiometric and catalytic reactivity. As part of this effort …
emerging strategy for eliciting new stoichiometric and catalytic reactivity. As part of this effort …
Facile Bismuth−Oxygen Bond Cleavage, C−H Activation, and Formation of a Monodentate Carbon-Bound Oxyaryl Dianion, (C6H2tBu2-3,5-O-4)2−
The Bi3+ (N, C, N)-pincer complex Ar′ BiCl2 (1)[Ar′= 2, 6-(Me2NCH2) 2C6H3], reacts with
2 equiv of KOC6H3Me2-2, 6 and KOC6H3 i Pr2-2, 6 by ionic metathesis to form the …
2 equiv of KOC6H3Me2-2, 6 and KOC6H3 i Pr2-2, 6 by ionic metathesis to form the …
Gold-and platinum-bismuth donor-acceptor interactions supported by an ambiphilic PBiP pincer ligand.
C Tschersich, C Limberg, S Roggan… - … (International ed. in …, 2012 - europepmc.org
Gold- and platinum-bismuth donor-acceptor interactions supported by an ambiphilic PBiP
pincer ligand. - Abstract - Europe PMC Sign in | Create an account https://orcid.org Europe …
pincer ligand. - Abstract - Europe PMC Sign in | Create an account https://orcid.org Europe …
Consequence of Ligand bite angle on bismuth lewis acidity
Ligand bite angle, a common parameter to fine-tune reactivity in transition-metal chemistry,
is used for the first time in main-group chemistry to control and tune the Lewis acidity in …
is used for the first time in main-group chemistry to control and tune the Lewis acidity in …
Neutral organoantimony (III) and organobismuth (III) ligands as acceptors in transition metal complexes–Role of substituents and co-ligands
SL Benjamin, G Reid - Coordination Chemistry Reviews, 2015 - Elsevier
This article reviews work up until mid-2014 on the synthesis and properties of transition
metal complexes containing the heavier Group 15 Sb (III) and Bi (III) ligands, of general …
metal complexes containing the heavier Group 15 Sb (III) and Bi (III) ligands, of general …
Probing the Limits of Oxidative Addition of C(sp3)–X Bonds toward Selected N,C,N-Chelated Bismuth(I) Compounds
M Hejda, R Jirásko, A Růžička, R Jambor… - …, 2020 - ACS Publications
The reactivity of two N, C, N-chelated bismuthinidenes, that is,[2, 6-(t BuN═ CH) 2C6H3] Bi
(1) and its metastable analogue [2, 6-(Me2NCH2) 2C6H3] Bi (2), toward organic substrates …
(1) and its metastable analogue [2, 6-(Me2NCH2) 2C6H3] Bi (2), toward organic substrates …
Unveiling the Electronic Structure of the Bi (+ 1)/Bi (+ 3) Redox Couple on NCN and NNN Pincer Complexes
M Gimferrer, S Danés, DM Andrada… - Inorganic …, 2021 - ACS Publications
Low-valent group 15 compounds stabilized by pincer ligands have gained particular
interest, given their direct access to fine-tune their reactivity by the coordination pattern …
interest, given their direct access to fine-tune their reactivity by the coordination pattern …
Dual Fluorescence and Phosphorescence Emissions from Dye-Modified (NCN)-Bismuth Pincer Thiolate Complexes
M Geppert, K Jellinek, M Linseis… - Inorganic …, 2024 - ACS Publications
We report the synthesis, characterization, and photophysical properties of four new dye-
modified (NCN) Bi pincer complexes with two mercaptocoumarin or mercaptopyrene …
modified (NCN) Bi pincer complexes with two mercaptocoumarin or mercaptopyrene …