As a straightforward strategy for rapidly increasing molecular complexity,
dicarbofunctionalization of alkenes has attracted substantial interests of organic synthesis …

1, 2-Dicarbofunctionalization of alkenes has emerged as an efficient synthetic strategy for
preparing substituted molecules by coupling readily available alkenes with electrophiles …

The development of general and efficient strategies for the construction of allenes is
important due to their wide applications. Although few protocols have been developed via …

An asymmetric 1, 2-dicarbofunctionalization of unactivated alkenes with aryl iodides and
aryl/alkenylboronic esters under nickel/bioxazoline catalysis is disclosed. A wide array of …

Transition metal‐catalyzed allylic substitution reactions represent versatile transformations
in organic synthesis forging C− C and C‐heteroatom bonds. Despite major contributions …

We disclose a Ni-catalyzed vicinal difunctionalization of alkenes with benzyl halides and
alkylzinc reagents, which produces products with two new alkyl–alkyl bonds. This alkene …

A multi-component approach to structurally complex organosulfur products is described via
the nickel-catalyzed 1, 2-carbosulfenylation of unactivated alkenes with organoboron …

Alkene 1, 2-dicarbofunctionalizations are highly sought-after transformations as they enable
a rapid increase of molecular complexity in one synthetic step. Traditionally, these …

Selective alkene dialkylation represents one of the most challenging transformations in
alkene difunctionalization reactions. Here, we report an excellent chemo-and regioselective …

We disclose a Ni-catalyzed vicinal alkylarylation of unactivated alkenes in γ, δ-
alkenylketimines with aryl halides and alkylzinc reagents. The reaction produces γ-C (sp3) …