Late-transition-metal catalysts have great potentials to incorporate polar comonomers during
olefin polymerization. The preparation of polar-functionalized polyolefins with different …

The transition-metal-catalyzed copolymerization of olefins with polar comonomers is a direct
strategy to access polar-functionalized polyolefins in an economical manner. Due to the …

Norbornene and derivatives represent an important class of comonomers in polyolefin
synthesis due to their unique cyclic structures. In this contribution, two groups of norbornene …

Vitrimers can combine the advantageous properties of cross-linked materials with
thermoplastic processability. For the prominent case of polyethylene, established post …

A series of palladium/alkylphosphine–sulfonate catalysts were synthesized and examined in
the homopolymerization of ethylene and the copolymerization of ethylene and polar …

Introducing polar biomass groups into polyolefins can not only improve their nonpolar nature
but also conform to the concept of sustainable development. Now, an efficient route to …

Highly active metallocenes and other single site catalysts as well as Grubbs and Schrock
metathesis catalytic systems have opened up the possibility to polymerize cycloolefins or to …

Because of their superior mechanical properties, excellent processability, reusability, and
recyclability, thermoplastic elastomers (TPEs) have attracted considerable research …

In this contribution, the effect of substitution on biaryl-based phosphine-sulfonate nickel
catalysts is investigated. A series of [κ2-(P, O)-2-(P-PhAr)-1-benzenesulfonato] NiPh (PPh3) …

Functionalization of polyolefins has been a challenging but promising issue since their
invention, with the promise of retaining inherent properties and overcoming the low reactivity …