The chemistry of transition‐metal (TM) complexes with monoanionic bidentate (κ2‐L, Si) silyl
ligands has considerably grown in recent years. This work summarizes the advances in the …

Cooperative dual site activation of boranes by redox-active 1, 3-N, S-chelated ruthenium
species, mer-[PR3 {κ2-N, S-(L)} 2Ru {κ1-S-(L)}],(mer-2a: R= Cy, mer-2b: R= Ph; L …

In an effort to investigate small molecule activation by heavier transition metal (TM) based κ2-
N, S-chelated species, we have synthesised a series of bis-κ2-1, 3-N, S-chelated complexes …

For a long time, the small group of cationic ligands stood out as an obscure phenomenon
within the general landscape of coordinative chemistry. However, this situation has started to …

Metal–ligand cooperativity (MLC), a phenomenon that leverages reactive ligands to promote
synergistic reactions with metals, has proven to be a powerful approach to achieving new …

In an effort to isolate diborane (4) derivatives, we have developed an efficient and
uncatalyzed approach using [BH3· THF] and the mercaptopyridine ligand. Thermolysis of 2 …

The synthesis and characterization of hydridoborate and hydridosilicate iron half-sandwich
complexes derived from activation of HBpin with an N2-bridged dimer [Cp* Fe (1, 2 …

We describe new compounds of stoichiometry M (CH2NMe2BH3) 3 (M= Ti, Cr, and Co),
each of which contains three chelating boranatodimethylaminomethyl (BDAM) ligands. In all …

In an effort to establish B‐P coupling reactions without the use of phosphine‐borane
dehydrocoupling agent, we have developed a new synthetic methodology employing group …

The industrialization of alkene hydrosilylation catalyzed by cheap metals has become a
research hotspot in recent years. Recently, we have found that [P, C] chelate cobalt (III) …