TADF: Enabling luminescent copper (i) coordination compounds for light-emitting electrochemical cells

CE Housecroft, EC Constable - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The last decade has seen a surge of interest in the emissive behaviour of copper (I)
coordination compounds, both neutral compounds that may have applications in organic …

Luminescent metal-organic frameworks and their composites: Potential future materials for organic light emitting displays

H Kaur, S Sundriyal, V Pachauri, S Ingebrandt… - Coordination Chemistry …, 2019 - Elsevier
Abstract Metal-Organic Frameworks (MOFs) are hybrid organic-inorganic materials with
enhanced electronic and optical functionalities that can be tailored by the judicious selection …

Efficient Reverse Intersystem Crossing in Carbene‐Copper‐Amide TADF Emitters via an Intermediate Triplet State

JP Zobel, AM Wernbacher… - Angewandte Chemie …, 2023 - Wiley Online Library
The mechanism behind reverse intersystem crossing (rISC) in metal‐based TADF emitters is
still under debate. Thermal rISC necessitates small singlet/triplet energy gaps as realized in …

Status and challenges of blue OLEDs: A review

I Siddiqui, S Kumar, YF Tsai, P Gautam, Shahnawaz… - Nanomaterials, 2023 - mdpi.com
Organic light-emitting diodes (OLEDs) have outperformed conventional display technologies
in smartphones, smartwatches, tablets, and televisions while gradually growing to cover a …

Room-temperature phosphorescence and thermally activated delayed fluorescence in the Pd complex: Mechanism and dual upconversion channels

ZW Li, LY Peng, XF Song, WK Chen… - The Journal of …, 2021 - ACS Publications
The Pd complex PdN3N exhibits an unusual dual emission of room-temperature
phosphorescence (RTP) and thermally activated delayed fluorescence (TADF), but the …

Pyridylarsine-based Cu (I) complexes showing TADF mixed with fast phosphorescence: a speeding-up emission rate using arsine ligands

AV Artem'ev, YV Demyanov, MI Rakhmanova… - Dalton …, 2022 - pubs.rsc.org
Can arsine ligands be preferred over similar phosphines to design Cu (I)-based TADF
materials? The present study reveals that arsines can indeed be superior to reach shorter …

Understanding the luminescence properties of Cu (I) complexes: a quantum chemical perusal

N Lüdtke, J Föller, CM Marian - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
Electronic structures and excited-state properties of Cu (I) complexes with varying
coordination numbers have been investigated by means of advanced quantum chemical …

Thermally Activated Delayed Fluorescence Mechanism of a Bicyclic “Carbene–Metal–Amide” Copper Compound: DFT/MRCI Studies and Roles of Excited-State …

XF Song, ZW Li, WK Chen, YJ Gao, G Cui - Inorganic Chemistry, 2022 - ACS Publications
Herein we investigated the luminescence mechanism of one “carbene–metal–amide”
copper compound with thermally activated delayed fluorescence (TADF) using density …

QM/MM studies on thermally activated delayed fluorescence of a dicopper complex in the solid state

LY Peng, W Chen, ZW Li, YJ Gao… - The Journal of Physical …, 2021 - ACS Publications
Dicopper complexes with thermally activated delayed fluorescence (TADF) phenomena are
important in enriching the arsenal of organic light-emitting diodes materials. However, the …

Ultrafast processes: coordination chemistry and quantum theory

C Daniel - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
Coordination compounds, characterized by fascinating and tunable electronic properties,
are capable of binding easily to proteins, polymers, wires and DNA. Upon irradiation, these …