The transition-metal (TM) chemistry of heavier tetrylenes (HTs), also known as heavier
carbene analogs, group 14 metalenes or group 14 metalylenes (compounds containing Si …

Since the late 19th century, heavier tetrylene-and tetrylyne-transition metal chemistry has
formed an important cornerstone in both main-group and organometallic chemistry alike …

Two synthetic approaches have until now been used to synthesize transition metal
complexes having a tridentate (pincer or tripod) PEP tetryl (E= Si, Ge, Sn) ligand. These …

A series of benzyl (diphenylphosphino) and o‐phenyl (diphenlyphosphino) substituted
germylenes and plumbylenes were synthesized by nucleophilic substitution between the …

We report a facile synthetic method for accessing rare T‐shaped Ni0 species, stabilised by
low‐coordinate cationic germylene and stannylene ligands which behave as Z‐type ligands …

Abstract Metal‐only Lewis pairs (MOLPs) in which the two metal fragments are solely
connected by a dative M→ M bond represent privileged architectures to acquire …

CAACs have emerged as an attractive class of ancillary ligands, forming strong bonds with
transition metals as well as main-group elements and stabilise both low and high oxidation …

Quantum chemical calculations at the BP86/TZVPP//BP86/SVP level are performed for the
tetrylone complexes [W (CO) 5‐E (PPh3) 2](W‐1 E) and the tetrylene complexes [W (CO) 5 …

Bermuda triangle: The first molecule containing a cyclic three‐membered Sn C P ring
has been synthesized and characterized. This SnII P Lewis pair reacts at room …

The synthesis of a silyliumylidene cation complex 2 stabilized by a Ni0‐based donating
ligand is reported. Experimental and theoretical studies demonstrate that the highly …