Recent advances in polyoxometalate-templated high-nuclear silver clusters

R Ge, XX Li, ST Zheng - Coordination Chemistry Reviews, 2021 - Elsevier
The search for feasible strategies to construct high-nuclear silver clusters has been
attracting continuous interests because such materials not only exhibit aesthetic structures …

Luminescence thermochromism in atomically precise silver clusters: A comprehensive review

YZ Huang, RK Gupta, GG Luo, QC Zhang… - Coordination Chemistry …, 2024 - Elsevier
Stimuli-responsive materials have garnered significant attention in technology, sensors, and
biological applications because of their quick response to various external factors. These …

Sulfide boosting near-unity photoluminescence quantum yield of silver nanocluster

SS Zhang, S Havenridge, C Zhang… - Journal of the …, 2022 - ACS Publications
Silver nanoclusters have emerged as promising candidates for optoelectronic applications,
but their room-temperature photoluminescence quantum yield (PLQY) is far from ideal to …

All-Carboxylate-Protected Superatomic Silver Nanocluster with an Unprecedented Rhombohedral Ag8 Core

KG Liu, XM Gao, T Liu, ML Hu… - Journal of the American …, 2020 - ACS Publications
We report the synthesis and structure of the first all-carboxylate-protected superatomic silver
nanocluster. It was prepared by heating a dimethylformamide solution of perfluoroglutaric …

Monocarboxylate-protected two-electron superatomic silver nanoclusters with high photothermal conversion performance

HH Wang, J Wei, F Bigdeli, F Rouhani, HF Su… - Nanoscale, 2023 - pubs.rsc.org
The first series of monocarboxylate-protected superatomic silver nanoclusters was
synthesized and fully characterized by X-ray diffraction, fourier-transform infrared …

Anionic passivation layer-assisted trapping of an icosahedral Ag13 kernel in a truncated tetrahedral Ag89 nanocluster

YM Su, BQ Ji, Z Wang, SS Zhang, L Feng… - Science China …, 2021 - Springer
Isolating reductive silver kernel from shell is a challenging task but is quite important to
understand the embryonic form during the formation of silver nanoclusters. The intercalation …

Discrete, Cationic Palladium (II)‐Oxo Clusters via f‐Metal Ion Incorporation and their Macrocyclic Host‐Guest Interactions with Sulfonatocalixarenes

S Bhattacharya, A Barba‐Bon… - Angewandte Chemie …, 2022 - Wiley Online Library
We report on the discovery of the first two examples of cationic palladium (II)‐oxo clusters
(POCs) containing f‐metal ions,[PdII6O12M8 {(CH3) 2AsO2} 16 (H2O) 8] 4+(M= CeIV, ThIV) …

A Two‐Electron Silver Superatom Isolated from Thermally Induced Internal Redox Reaction of A Silver (I) Hydride

YJ Zhong, JH Liao, TH Chiu, S Kahlal… - Angewandte Chemie …, 2021 - Wiley Online Library
Rational syntheses under controllable reducing conditions in the preparation of superatoms
with cluster electron number not exceeding two are challenging. Herein a dithiolate …

Hexavalent octahedral template: a neutral high-nucleus silver alkynyl nanocluster emitting infrared light

KG Liu, F Bigdeli, HJ Li, JZ Li, XW Yan, ML Hu… - Inorganic …, 2020 - ACS Publications
The first silver nanocluster with an octahedral template of TeO66–was synthesized as a
neutral 36-nucleus nanocluster, and its structure was demonstrated using single-crystal X …

Snapshots of key intermediates unveiling the growth from silver ions to Ag70 nanoclusters

XM Luo, S Huang, P Luo, K Ma, ZY Wang, XY Dong… - Chemical …, 2022 - pubs.rsc.org
Nanoclusters (NCs) are considered as initial states of condensed matter, and unveiling their
formation mechanism is of great importance for directional synthesis of nanomaterials. Here …