Advanced supramolecular design for direct ink writing of soft materials

M Tang, Z Zhong, C Ke - Chemical Society Reviews, 2023 - pubs.rsc.org
The exciting advancements in 3D-printing of soft materials are changing the landscape of
materials development and fabrication. Among various 3D-printers that are designed for soft …

In Situ Covalent Reinforcement of a Benzene‐1, 3, 5‐Tricarboxamide Supramolecular Polymer Enables Biomimetic, Tough, and Fibrous Hydrogels and Bioinks

S Hafeez, MC Decarli, A Aldana, M Ebrahimi… - Advanced …, 2023 - Wiley Online Library
Synthetic hydrogels often lack the load‐bearing capacity and mechanical properties of
native biopolymers found in tissue, such as cartilage. In natural tissues, toughness is often …

Mimicking the extracellular world: From natural to fully synthetic matrices utilizing supramolecular biomaterials

L Rijns, M Rutten, A Vrehen, A Aldana, M Baker… - Nanoscale, 2024 - pubs.rsc.org
The extracellular matrix (ECM) has evolved around complex covalent and non-covalent
interactions to create impressive function—from cellular signaling to constant remodeling. A …

Molecular Tuning of a Benzene‐1, 3, 5‐Tricarboxamide Supramolecular Fibrous Hydrogel Enables Control over Viscoelasticity and Creates Tunable ECM‐Mimetic …

S Hafeez, AA Aldana, H Duimel, FAA Ruiter… - Advanced …, 2023 - Wiley Online Library
Traditional synthetic covalent hydrogels lack the native tissue dynamics and hierarchical
fibrous structure found in the extracellular matrix (ECM). These dynamics and fibrous …

C− H Functionalization and Allylic Amination for Post‐Polymerization Modification of Polynorbornenes

SR Gitter, WP Teh, X Yang, AF Dohoda… - Angewandte Chemie …, 2023 - Wiley Online Library
Post‐polymerization modification (PPM) via direct C− H functionalization is a powerful
synthetic strategy to convert polymer feed‐stocks into value‐added products. We found that …

Access to Functionalized Materials by Metal-Free Ring-Opening Metathesis Polymerization of Active Esters and Divergent Postpolymerization Modification

SR Gitter, R Li, AJ Boydston - ACS Macro Letters, 2024 - ACS Publications
Metal-free ring-opening metathesis polymerization (MF-ROMP) is an emerging
polymerization strategy that provides access to ROMP materials by using organic initiators …

Polymeric membranes with highly homogenized nanopores for ultrafast water purification

J Huang, Y Zhang, J Guo, F Yang, J Ma, Y Bai… - Nature …, 2024 - nature.com
Membrane nanofiltration is widely used in various chemical separation and water
purification processes. However, obtaining high water permeance and high solute removal …

Importance of Molecular and Bulk Dynamics in Supramolecular Hydrogels in Dictating Cellular Spreading

L Rijns, JW Peeters, SIS Hendrikse… - Chemistry of …, 2023 - ACS Publications
Cellular spreading is affected not only by the stiffness of the matrix but also by its dynamics.
Synthetic hydrogels, formed by the assembly of supramolecular monomers, are intrinsically …

One-pot synthesis of double-network PEG/collagen hydrogel for enhanced adipogenic differentiation and retrieval of adipose-derived stem cells

H Lee, HJ Hong, S Ahn, D Kim, SH Kang, K Cho… - Polymers, 2023 - mdpi.com
Hydrogels are widely used in stem cell therapy due to their extensive tunability and
resemblance to the extracellular matrix (ECM), which has a three-dimensional (3D) …

Dynamic Peptide Nanoframework-Guided Protein Coassembly: Advancing Adhesion Performance with Hierarchical Structures

Y Zhou, R Chang, Z Yang, Q Guo, M Wang… - Journal of the …, 2025 - ACS Publications
Hierarchical structures are essential in natural adhesion systems. Replicating these in
synthetic adhesives is challenging due to intricate molecular mechanisms and multiscale …