Rate coefficients of free-radical polymerization deduced from pulsed laser experiments

S Beuermann, M Buback - Progress in Polymer Science, 2002 - Elsevier
Pulsed laser techniques have enormously improved the quality by which rate coefficients of
individual steps in free-radical polymerization may be measured. Pulsed laser initiated …

RAFT polymerization of vinyl esters: synthesis and applications

S Harrisson, X Liu, JN Ollagnier, O Coutelier, JD Marty… - Polymers, 2014 - mdpi.com
This article is the first comprehensive review on the study and use of vinyl ester monomers in
reversible addition fragmentation chain transfer (RAFT) polymerization. It covers all the …

Critically evaluated rate coefficients for free‐radical polymerization, 1. Propagation rate coefficient for styrene

M Buback, RG Gilbert, RA Hutchinson… - Macromolecular …, 1995 - Wiley Online Library
Pulsed‐laser polymerization (PLP) in conjugation with molecular weight distribution (MWD)
measurement has emerged as the method of choice for determining the propagation rate …

Critically evaluated rate coefficients for free‐radical polymerization, 2.. Propagation rate coefficients for methyl methacrylate

S Beuermann, M Buback, TP Davis… - Macromolecular …, 1997 - Wiley Online Library
Pulsed‐laser polymerization (PLP) in conjunction with molar mass distribution (MMD)
measurement is the method of choice for determining the propagation rate coefficient kp in …

Determination of free-radical propagation rate coefficients of butyl, 2-ethylhexyl, and dodecyl acrylates by pulsed-laser polymerization

S Beuermann, DA Paquet, JH McMinn… - …, 1996 - ACS Publications
Analysis of the molecular weight distributions (MWDs) of polymer produced by pulsed-laser
polymerization (PLP) is an effective method for the determination of free-radical propagation …

Complex macromolecular architectures by reversible addition fragmentation chain transfer chemistry: theory and practice

L Barner, TP Davis, MH Stenzel… - Macromolecular …, 2007 - Wiley Online Library
Reversible addition–fragmentation chain transfer (RAFT) chemistry can be effectively
employed to construct macromolecular architectures of varying topologies. The present …

Pressure dependence of propagation rate coefficients in free‐radical homopolymerizations of methyl acrylate and dodecyl acrylate

M Buback, CH Kurz, C Schmaltz - … Chemistry and Physics, 1998 - Wiley Online Library
Propagation rate coefficients (kp) for the homopolymerization of methyl acrylate (MA) and
dodecyl acrylate (DA) were determined by the pulsed laser polymerization (PLP)/size …

Pulsed-laser polymerization measurements of the propagation rate coefficient for butyl acrylate

RA Lyons, J Hutovic, MC Piton, DI Christie… - …, 1996 - ACS Publications
The results are reported for a series of measurements of the propagation rate coefficient (kp)
of butyl acrylate obtained from pulsed-laser polymerization (PLP). Previous attempts …

Critically evaluated termination rate coefficients for free-radical polymerization: Experimental methods

C Barner-Kowollik, M Buback, M Egorov… - Progress in polymer …, 2005 - Elsevier
The knowledge of accurate rate coefficients for individual steps of free-radical
polymerization (FRP) is of scientific interest and of application-oriented importance. For a …

Propagation kinetics of acrylic and methacrylic acid in water and organic solvents studied by pulsed-laser polymerization

FD Kuchta, AM van Herk, AL German - Macromolecules, 2000 - ACS Publications
Pulsed laser-induced polymerization (PLP) in combination with analysis of formed polymer
by size exclusion chromatography (SEC) has been successfully applied in determining …