Understanding and development of olivine LiCoPO 4 cathode materials for lithium-ion batteries

M Zhang, N Garcia-Araez, AL Hector - Journal of Materials Chemistry …, 2018 - pubs.rsc.org
Olivine LiCoPO4 is a promising candidate as the cathode material for high-voltage lithium-
ion batteries due to its high redox potential of 4.8 V vs. Li/Li+ and a theoretical capacity of …

Recent progress and developments in lithium cobalt phosphate chemistry-Syntheses, polymorphism and properties

J Ludwig, T Nilges - Journal of Power Sources, 2018 - Elsevier
This review summarizes the development, investigation, and optimization of polymorphic
lithium cobalt phosphate LiCoPO 4. One of the three polymorphs known to date, olivine-type …

Morphology-controlled microwave-assisted solvothermal synthesis of high-performance LiCoPO4 as a high-voltage cathode material for Li-ion batteries

J Ludwig, C Marino, D Haering, C Stinner… - Journal of Power …, 2017 - Elsevier
High-performance particles of the high-voltage cathode material LiCoPO 4 for Li-ion
batteries are synthesized by a simple and rapid one-step microwave-assisted solvothermal …

Li (Ni, Co) PO4 as cathode materials for lithium batteries: Will the dream come true?

A Mauger, CM Julien, M Armand… - Current Opinion in …, 2017 - Elsevier
Among the lithium-transition metal phosphates, LiFePO 4 is an important cathode material
both for Li-ion and Li-metal batteries, due to its very good thermal stability, safety, low cost …

Enhancement of the electrochemical performance of LiCoPO4 by Fe doping

AM Aboraia, MG Moustafa, VV Shapovalov… - Ceramics …, 2021 - Elsevier
LiCoPO 4 is an attractive cathode material, but it undergoes poor electronic conductivity and
electrochemical performance. This performance is enhanced by substituting iron antisite …

Interplay between local structure and transport properties in iron-doped LiCoPO 4 olivines

S Brutti, J Manzi, D Meggiolaro, FM Vitucci… - Journal of Materials …, 2017 - pubs.rsc.org
LiCoPO4 (LCP) is a challenging high voltage positive electrode material for next-generation
secondary Li-ion cells. Doping the LCP olivine lattice with iron and annealing the material at …

Surface chemistry on LiCoPO4 electrodes in lithium cells: SEI formation and self-discharge

J Manzi, S Brutti - Electrochimica Acta, 2016 - Elsevier
In this manuscript we investigate the surface chemistry of positive electrodes for Li-ion cell
applications constituted by LiCoPO 4 (LCP). This high potential material reversibly de …

Structural evolution of disordered LiCo 1/3 Fe 1/3 Mn 1/3 PO 4 in lithium batteries uncovered

AB Muñoz-García, B Tirri, I Capone, A Matic… - Journal of Materials …, 2020 - pubs.rsc.org
In this study we address the Li-ion de-insertion/insertion mechanisms from/into the lattice of
the mixed olivine LiCo1/3Fe1/3Mn1/3PO4 (LCFMP). This mechanism is driven by a subtle …

Facile, ethylene glycol-promoted microwave-assisted solvothermal synthesis of high-performance LiCoPO 4 as a high-voltage cathode material for lithium-ion …

J Ludwig, C Marino, D Haering, C Stinner… - RSC …, 2016 - pubs.rsc.org
Olivine-type LiCoPO4 is considered a promising high-voltage cathode material for next-
generation lithium-ion batteries. However, preparing high-performance LiCoPO4 by a …

Distinguishing the Intrinsic Antiferromagnetism in Polycrystalline LiCoPO4 and LiMnPO4 Olivines

S Gnewuch, EE Rodriguez - Inorganic Chemistry, 2020 - ACS Publications
We report a detailed investigation of the long-range magnetic ordering in polycrystalline
samples of LiCoPO4 and LiMnPO4, which belong to a series of well-known olivine cathode …