Spin hyperpolarization in modern magnetic resonance

J Eills, D Budker, S Cavagnero, EY Chekmenev… - Chemical …, 2023 - ACS Publications
Magnetic resonance techniques are successfully utilized in a broad range of scientific
disciplines and in various practical applications, with medical magnetic resonance imaging …

Solid-state NMR investigations of extracellular matrixes and cell walls of algae, bacteria, fungi, and plants

N Ghassemi, A Poulhazan, F Deligey… - Chemical …, 2021 - ACS Publications
Extracellular matrixes (ECMs), such as the cell walls and biofilms, are important for
supporting cell integrity and function and regulating intercellular communication. These …

Lignin-polysaccharide interactions in plant secondary cell walls revealed by solid-state NMR

X Kang, A Kirui, MC Dickwella Widanage… - Nature …, 2019 - nature.com
Lignin is a complex aromatic biopolymer that strengthens and waterproofs plant secondary
cell walls, enabling mechanical stability in trees and long-distance water transport in xylem …

Biomolecular and biological applications of solid-state NMR with dynamic nuclear polarization enhancement

WY Chow, G De Paëpe, S Hediger - Chemical Reviews, 2022 - ACS Publications
Solid-state NMR spectroscopy (ssNMR) with magic-angle spinning (MAS) enables the
investigation of biological systems within their native context, such as lipid membranes, viral …

Recent developments in MAS DNP-NMR of materials

AGM Rankin, J Trébosc, F Pourpoint… - Solid State Nuclear …, 2019 - Elsevier
Solid-state NMR spectroscopy is a powerful technique for the characterization of the atomic-
level structure and dynamics of materials. Nevertheless, the use of this technique is often …

Hyperpolarized water as universal sensitivity booster in biomolecular NMR

C Hilty, D Kurzbach, L Frydman - Nature protocols, 2022 - nature.com
NMR spectroscopy is the only method to access the structural dynamics of biomolecules at
high (atomistic) resolution in their native solution state. However, this method's low …

Efficient dynamic nuclear polarization at 800 MHz/527 GHz with trityl‐nitroxide biradicals

G Mathies, MA Caporini, VK Michaelis… - Angewandte Chemie …, 2015 - Wiley Online Library
Cross‐effect (CE) dynamic nuclear polarization (DNP) is a rapidly developing technique that
enhances the signal intensities in magic‐angle spinning (MAS) NMR spectra. We report CE …

Nuclear depolarization and absolute sensitivity in magic-angle spinning cross effect dynamic nuclear polarization

F Mentink-Vigier, S Paul, D Lee, A Feintuch… - Physical Chemistry …, 2015 - pubs.rsc.org
Over the last two decades solid state Nuclear Magnetic Resonance has witnessed a
breakthrough in increasing the nuclear polarization, and thus experimental sensitivity, with …

TinyPols: a family of water-soluble binitroxides tailored for dynamic nuclear polarization enhanced NMR spectroscopy at 18.8 and 21.1 T

A Lund, G Casano, G Menzildjian, M Kaushik… - Chemical …, 2020 - pubs.rsc.org
Dynamic Nuclear Polarization (DNP) has recently emerged as a key method to increase the
sensitivity of solid-state NMR spectroscopy under Magic Angle Spinning (MAS). While …

Dynamic nuclear polarization solid-state NMR spectroscopy for materials research

IB Moroz, M Leskes - Annual Review of Materials Research, 2022 - annualreviews.org
Solid-state nuclear magnetic resonance (NMR) spectroscopy has increasingly been used for
materials characterization as it enables selective detection of elements of interest, as well as …