Transition metals, which are of diversity in their bonding orbitals, have a variety of significant
oxidation states and more complex chemical properties compared to the main group metals …

Fundamental research on germanium as the central element in compounds for bond
activation chemistry and catalysis has achieved significant feats over the last two decades …

Chiral 2-substituted imidazolines are not only privileged scaffolds in many bioactive
compounds, but they are also widely used as ligands and catalysts in asymmetric synthesis …

The unique properties of lanthanoids and their diverse applications make them an
indispensable part of modern research and industry. While the field has garnered attention …

The intermolecular anti‐Markovnikov hydroamination of vinylsilanes was achieved utilizing
five silyl‐substituted ortho‐terphenoxide yttrium complexes. The highest activity was …

An exclusive anti‐Markovnikov hydroamination as well as hydroalkoxylation of allylic
alcohols catalyzed by a simple catalyst Y (CH2SiMe3) 3 (THF) 2 has been developed …

For over a century, the Tishchenko reaction has been a valuable technique for synthesizing
esters from aldehydes, serving a variety of applications in different domains. Beyond the …

Rare earth tris (alkyl) complexes such as M (CH2SiMe3) 3 (sol) n are widely used as
precursors for many compounds and as homogeneous catalysts for alkene polymerization …

Enantioselective addition of an imide N–H bond to alkenes was realized by use of a cationic
iridium catalyst. Bulky diphosphine ligands such as DTBM-segphos, DTBM-MeO-biphep …

A photochemical method based on visible‐light irradiation (blue LEDs/sunlight) has been
developed for the intermolecular hydroamination and hydroetherification of electron‐rich …