Click nucleophilic conjugate additions to activated alkynes: exploring thiol-yne, amino-yne, and hydroxyl-yne reactions from (bio) organic to polymer chemistry

JC Worch, CJ Stubbs, MJ Price, AP Dove - Chemical Reviews, 2021 - ACS Publications
The 1, 4-conjugate addition reaction between activated alkynes or acetylenic Michael
acceptors and nucleophiles (ie, the nucleophilic Michael reaction) is a historically useful …

Stereochemical enhancement of polymer properties

JC Worch, H Prydderch, S Jimaja, P Bexis… - Nature Reviews …, 2019 - nature.com
The importance of stereochemistry to the function of molecules is generally well understood.
However, to date, control over stereochemistry and its potential to influence properties of the …

X‐yne click polymerization

X Fu, A Qin, BZ Tang - Aggregate, 2023 - Wiley Online Library
Alkyne‐based click polymerizations have been nurtured into a powerful synthetic technique
for the preparation of new polymers with advanced structures and versatile properties …

Wound microenvironment-responsive protein hydrogel drug-loaded system with accelerating healing and antibacterial property

R Zhang, Y Tian, L Pang, T Xu, B Yu… - … Applied Materials & …, 2022 - ACS Publications
Growth factors play a vital role in wound healing, and novel hydrogel carriers suitable for
growth factors have always been a research hotspot in the wound healthcare field. In this …

Pyridyl disulfide-based thiol–disulfide exchange reaction: Shaping the design of redox-responsive polymeric materials

I Altinbasak, M Arslan, R Sanyal, A Sanyal - Polymer Chemistry, 2020 - pubs.rsc.org
Recent years have witnessed an increase in the utilization of stimuli-responsive polymers in
various areas of materials and biological sciences. In particular, disulfide linkage containing …

Nucleophilic Thiol-yne reaction in Macromolecular Engineering: From synthesis to applications

O Daglar, S Luleburgaz, E Baysak, US Gunay… - European Polymer …, 2020 - Elsevier
The developments in synthetic polymer chemistry have devoted to meet the huge demand
required to create efficient, high yield, and operationally simple chemical methods that can …

Rapeseed oil as feedstock for the polymeric materials via Michael addition reaction

A Abolins, D Eihe, R Pomilovskis, A Fridrihsone… - Industrial Crops and …, 2023 - Elsevier
Rapeseed oil was used to synthesize a Michael donor to obtain polymeric materials after
nucleophilic polymerization via Michael reaction. Four different bio-polyols as precursors for …

Extremely rapid polythioether synthesis in the presence of TBD

O Daglar, US Gunay, G Hizal, U Tunca… - Macromolecules, 2019 - ACS Publications
A straightforward, novel, and extremely rapid method is developed for the synthesis of
polythioether based on the reaction of dimethyl acetylenedicarboxylate with electron …

New Horizon in Phospha-Michael Reaction: Ultrafast Double Addition of P–H Bond-Bearing Nucleophiles to Electron-Deficient Triple Bonds and Its Use for Functional …

G Sagdic, O Daglar, E Cakmakci, V Findik… - …, 2023 - ACS Publications
In this work, a novel, straightforward, robust, fast, and organocatalyst-mediated phospha-
Michael reaction (OCPMR) was developed for the addition of phosphorus nucleophiles to …

Thermal and mechanical properties of thiol-ene photocured thermosets containing DOPO-based liquid reactive flame retardant synthesized by metal-free azide-alkyne …

G Sagdic, E Cakmakci, O Daglar, US Gunay… - Progress in Organic …, 2022 - Elsevier
The use of metal-free click reactions for the design and synthesis of novel flame retardant
reactive monomers for thiol-ene photopolymerization is an intriguing area of research. In this …