Structure and dynamics of interfacial peptides and proteins from vibrational sum-frequency generation spectroscopy

S Hosseinpour, SJ Roeters, M Bonn, W Peukert… - Chemical …, 2020 - ACS Publications
Proteins at interfaces play important roles in cell biology, immunology, bioengineering, and
biomimetic material design. Many biological processes are based on interfacial protein …

[HTML][HTML] Carbonation mechanisms and kinetics of lime-based binders: An overview

C Rodriguez-Navarro, T Ilić, E Ruiz-Agudo… - Cement and Concrete …, 2023 - Elsevier
The reaction of slaked lime with atmospheric CO 2 in the presence of humidity leads to the
formation of cementing carbonate phases in traditional aerial lime mortars and plasters. This …

New horizons of nonclassical crystallization

M Jehannin, A Rao, H Cölfen - Journal of the American …, 2019 - ACS Publications
Nonclassical crystallization (NCC) summarizes a number of crystallization pathways, which
differ from the classical layer-by-layer growth of crystals involving atomic/molecular building …

Microscopic structure of the polymer-induced liquid precursor for calcium carbonate

Y Xu, KCH Tijssen, PHH Bomans, A Akiva… - Nature …, 2018 - nature.com
Many biomineral crystals form complex non-equilibrium shapes, often via transient
amorphous precursors. Also in vitro crystals can be grown with non-equilibrium …

Formation, chemical evolution and solidification of the dense liquid phase of calcium (bi) carbonate

B Jin, Y Chen, H Pyles, MD Baer, BA Legg, Z Wang… - Nature Materials, 2024 - nature.com
Metal carbonates, which are ubiquitous in the near-surface mineral record, are a major
product of biomineralizing organisms and serve as important targets for capturing …

Multi-step nucleation pathway of CSH during cement hydration from atomistic simulations

XM Aretxabaleta, J López-Zorrilla, I Etxebarria… - Nature …, 2023 - nature.com
Abstract The Calcium Silicate Hydrate (CSH) nucleation is a crucial step during cement
hydration and determines to a great extent the rheology, microstructure, and properties of …

Hybrid scanning electrochemical cell microscopy-interference reflection microscopy (SECCM-IRM): tracking phase formation on surfaces in small volumes

D Valavanis, P Ciocci, GN Meloni, P Morris… - Faraday …, 2022 - pubs.rsc.org
We describe the combination of scanning electrochemical cell microscopy (SECCM) and
interference reflection microscopy (IRM) to produce a compelling technique for the study of …

Designing solid materials from their solute state: a shift in paradigms toward a holistic approach in functional materials chemistry

D Gebauer, SE Wolf - Journal of the American Chemical Society, 2019 - ACS Publications
“Non-classical” notions consider formation pathways of crystalline materials where larger
species than monomeric chemical constituents, ie, ions or single molecules, play crucial …

A tale of two foulants: the coupling of organic fouling and mineral scaling in membrane desalination

T Tong, X Liu, T Li, S Park, B Anger - Environmental Science & …, 2023 - ACS Publications
Membrane desalination that enables the harvesting of purified water from unconventional
sources such as seawater, brackish groundwater, and wastewater has become …

[PDF][PDF] On classical and non-classical views on nucleation

D Gebauer, P Raiteri, JD Gale, H Cölfen - American Journal of …, 2018 - ajsonline.org
Classical nucleation theory (CNT) is based on the notion of critical nuclei serving as
transition states between supersaturated solutions and growing particles. Their excess …