Applications of transition metal amidinate [RC (NR′) 2], guanidinate and amidopyridine
complexes to olefin coordination polymerization are reviewed. In addition, the use of …

Organometallic chemistry has provided the foundation for the development of a wide range
of new olefin polymerization catalysts over the last two to three decades. The unraveling of …

Highly efficient, living coordinative chain-transfer polymerization (CCTP) of propene can be
conducted with the highly active catalyst derived from equimolar amounts of (η5-C5Me5) Hf …

A comparison of the steric properties of homogeneous single site catalysts for propene
polymerization using the percentage of buried volume (% V Bur) as molecular descriptor is …

The design of catalysts that will enable the living polymerization of propylene with high
activities and isoselectivities under ambient conditions remains a challenge in current …

Computational studies of a variety of polymerization catalyst models have revealed an
unexpected fluidity in chain termination mechanisms. For many early transition metal olefin …

Achieving the detailed knowledge of recycled materials composition is a formidable task due
to the presence of organic and inorganic contaminations. Additionally, the complexity of the …

The effect of type and concentration of external donor and hydrogen concentration on
oligomer formation and chain end distribution were studied. Bulk polymerization of …

Olefin plastomers/elastomers are typically copolymers with high comonomer contents and
low crystallinities. Therefore, the fractionation of these materials with crystallization‐based …

The “comonomer effect” is an intriguing kinetic phenomenon in olefin copolymerization that
still remains without a detailed explanation. It typically relates to the rate of enhancement …