Synthetic organic reactions involving gaseous reagents are frequently avoided in the
research lab for practical and safety reasons. Nevertheless, reactive gases often represent …

A broad‐spectrum, catalytic method has been developed for the synthesis of sulfonamides
and sulfamates. With the activation by the combination of a catalytic amount of 1 …

Conventional direct C− H selenylation suffers from simple selenation with limited atom
economy and complicated reaction system. In this work, we designed benzoselenazolone …

Access to SuFExable compounds was remarkably simplified by introduction of the solid
FO2S-donor SuFEx-IT. However, the published process for preparation of this reagent relies …

Accelerated SuFEx Click Chemistry (ASCC) is a powerful method for coupling aryl and alkyl
alcohols with SuFEx-compatible functional groups. With its hallmark favorable kinetics and …

We report a general palladium-catalyzed one-pot procedure for the synthesis of
phosphonates, phosphinates and phosphine oxides from phenols mediated by sulfuryl …

Aryl fluorosulfates of varying complexities have been used in amination reactions in water
using a new Pd oxidative addition complex (OAC‐1) developed specifically to match the …

Two efficient transition-metal-free highly regioselective pathways for constructing
sulfonylated imidazoles via three-component reactions of amidines, ynals, and sodium …

A hydroamination of unactivated alkynes and lithium bis (fluorosulfonyl) imide (LiN (SO2F)
2) is described under mild conditions, affording a single regioisomer of the sulfonyl fluorides …

The first general route toward polysubstituted ferrocenesulfonyl fluorides is described.
Merging deprotometallations,'halogen dance'reaction, Sonogashira, Suzuki–Miyaura and …