Challenges and Strategies towards Single‐Crystalline Ni‐Rich Layered Cathodes

L Ni, S Zhang, A Di, W Deng, G Zou… - Advanced Energy …, 2022 - Wiley Online Library
The ever‐increasing energy density requirements in electric vehicles (EVs) have boosted
the development of Ni‐rich layered oxide cathodes for state‐of‐the‐art lithium‐ion batteries …

Single‐crystalline cathodes for advanced Li‐ion batteries: progress and challenges

Y Han, Y Lei, J Ni, Y Zhang, Z Geng, P Ming, C Zhang… - Small, 2022 - Wiley Online Library
Single‐crystalline cathodes are the most promising candidates for high‐energy‐density
lithium‐ion batteries (LIBs). Compared to their polycrystalline counterparts, single‐crystalline …

[HTML][HTML] Crack-free single-crystalline Co-free Ni-rich LiNi0. 95Mn0. 05O2 layered cathode

L Ni, R Guo, S Fang, J Chen, J Gao, Y Mei, S Zhang… - eScience, 2022 - Elsevier
The rapid growth in global electric vehicles (EVs) sales has promoted the development of
Co-free, Ni-rich layered cathodes for state-of-the-art high energy-density, inexpensive …

The surface double-coupling on single-crystal LiNi0. 8Co0. 1Mn0. 1O2 for inhibiting the formation of intragranular cracks and oxygen vacancies

Y Liu, T Zeng, G Li, T Wan, M Li, X Zhang, M Li… - Energy Storage …, 2022 - Elsevier
Abstract Single-crystal LiNi 0.8 Co 0.1 Mn 0.1 O 2 (SC-811), which prevents grain-boundary
fracture and offers better cycle performance compared to the polycrystalline morphology …

Competitive Doping Chemistry for Nickel‐Rich Layered Oxide Cathode Materials

YJ Guo, CH Zhang, S Xin, JL Shi, WP Wang… - Angewandte …, 2022 - Wiley Online Library
Chemical modification of electrode materials by heteroatom dopants is crucial for improving
storage performance in rechargeable batteries. Electron configurations of different dopants …

Morphology-dependent battery performance of Ni-rich layered cathodes: Single-crystal versus refined polycrystal

HH Ryu, SB Lee, CS Yoon, YK Sun - ACS Energy Letters, 2022 - ACS Publications
Single-crystal, conventional, and refined polycrystalline (Li [Ni0. 9Co0. 05Mn0. 05] O2)
cathodes were prepared, and their performances and capacity fading behaviors in half cells …

Significantly fastened redox kinetics in single crystal layered oxide cathode by gradient doping

S Jamil, M Fasehullah, B Jabar, P Liu, MK Aslam… - Nano Energy, 2022 - Elsevier
Nickel-rich layered cathode is a forefront candidate for lithium-ion batteries; however,
structural degradation such as intragranular cracking and phase transition in polycrystals …

Chemomechanically Stable Small Single‐crystal Mo‐doped LiNi0.6Co0.2Mn0.2O2 Cathodes for Practical 4.5 V‐class Pouch‐type Li‐ion Batteries

L Liang, X Li, M Su, L Wang, J Sun, Y Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
High voltage can cost‐effectively boost energy density of Ni‐rich cathodes based Li‐ion
batteries (LIBs), but compromises their mechanical, electrochemical and thermal‐driven …

Design and mechanism exploration of single-crystalline NCM811 materials with superior comprehensive performance for Li-ion batteries

X Kong, H Yang, Y Zhang, P Dai, Y Tang, J Zeng… - Chemical Engineering …, 2023 - Elsevier
Although single-crystalline LiNi x Co y Mn 1-xy O 2 (SC NCM) materials have been
confirmed to have advantages in cycle performance, storage performance and thermal …

Unveiling the impact of residual Li conversion and cation ordering on electrochemical performance of Co-free Ni-rich cathodes

C Wang, L Tan, H Yi, Z Zhao, X Yi, Y Zhou, J Zheng… - Nano Research, 2022 - Springer
Abstract The residual Li and Li+/Ni2+ cation mixing play essential roles in the
electrochemical properties of Ni-rich cathodes. However, a general relationship between the …