Organomagnesium reagents occupy a central position in synthetic organic and
organometallic chemistry. Recently, the halogen–magnesium exchange has considerably …

Magnesiumverbindungen spielen eine zentrale Rolle in der präparativen organischen und
metallorganischen Chemie. Seit kurzem ermöglicht der Halogen‐Magnesium‐Austausch …

Halogen− magnesium exchange of various aryl halides is achieved with a magnesium ate
complex at low temperatures. Tributylmagnesate (n Bu3MgLi) induces facile iodine …

Halogen-bonded complexes are utilized across a myriad of synthetic chemistry fields, with
halogen (I) complexes such as Barluenga's reagent being ubiquitous in halogenation …

In the last few years, we have demonstrated that the halogen/magnesium-exchange reaction
is a unique method for preparing a variety of new functionalized aryl, alkenyl, heteroaryl …

A facile and efficient oxidative C− H acylation of N‐substituted pyrazolones using α‐
oxocarboxylic acids as an acyl group source was developed. A combination of Cu (OAc) 2 …

The pyrrole-imidazole family of marine alkaloids, the so-called oroidin natural products,
exhibits an impressive diversity of structural motifs. The majority of these natural products …

Copper-catalyzed direct acylation of the alkenyl C–H bond in 1, 2-dihydro-3H-pyrazol-3-
ones has been developed, affording a series of 4-acylpyrazolones in moderate to good …

Concise total synthesis of naamine G and naamidine H - Chemical Communications (RSC
Publishing) DOI:10.1039/B926285G Royal Society of Chemistry ViewáPDFáVersionPreviousáArticleNextáArticle …

The total synthesis of a number of representative natural products isolated from Leucetta
and Clathrina sponges containing a polysubstituted 2-aminoimidazole are described. These …