Acceptorless dehydrogenative coupling reactions has emerged as one of the promising
technique in synthetic organic chemistry to construct carbon‐carbon and carbon‐heteroatom …

Homogeneous catalysis of organic transformations by metal complexes has been mostly
based on complexes of noble metals. In recent years, tremendous progress has been made …

Amides are undeniably some of the most important compounds in Nature and the chemical
industry, being present in biomolecules, materials, pharmaceuticals and many other …

The first example of a base metal (manganese) catalyzed acceptorless dehydrogenative
coupling of methanol and amines to form formamides is reported herein. The novel pincer …

Various primary amides have been synthesized using the transamidation of various tertiary
amides under metal-free and mild reaction conditions. When (NH4) 2CO3 reacts with a …

A commercially available and versatile dehydrative amidation catalyst, featuring a
thianthrene boron acid structure, has been developed. The catalyst shows high catalytic …

2, 4-Bis (trifluoromethyl) phenylboronic acid is a highly effective catalyst for dehydrative
amidation between carboxylic acids and amines. Mechanistic studies suggest that a 2: 2 …

The departure into unknown chemical space is essential for the discovery of new properties
and function. We herein report the first synthetic access to N‐trifluoromethylated formamides …

Carboxylic acids and their corresponding carboxylate anions are generally utilized as
Brønsted acids/bases and oxygen nucleophiles in organic synthesis. However, a few …

A simple catalyst-and promoter-free protocol has been developed for the transamidation of
weakly nucleophilic aromatic amines with formamide derivatives and low-reactivity tertiary …