Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

Even though the existence of 1, 2, 3‐triazoles has been known for more than a century, the
recent discovery of a copper (I) catalyzed version of this reaction has attributed …

Mesoionic carbenes have found wide use as components of homogeneous catalysts.
Recent discoveries have, however, shown that metal complexes of such ligands also have …

Bidentate ligands containing at least one triazole or triazolylidene (mesoionic carbene, MIC)
unit are extremely popular in contemporary chemistry. One reason for their popularity is the …

Beyond the classic N-heterocyclic carbenes (NHCs) there is a subclass of NHCs called
mesoionic carbenes (MICs). This review focuses on recent advances in the area of 1, 2, 3 …

Tricarbonyl Group 7 complexes have a longstanding history as efficacious CO2
electroreduction catalysts. Typically, these complexes feature an auxiliary 2, 2′-bipyridine …

Imidazol-2-ylidene (ImNHC) and 1, 2, 3-traizol-5-ylidene (tzNHC) have been established as
important classes of carbene ligands in homogeneous catalysis. To develop Ru (II)/Ir (III) …

We report the synthesis of vanadium (V) oxo complex 1 with a pincer-type dianionic
mesoionic carbene (MIC) ligand L 1 and the general formula [VOCl (L1)]. A comparison of …

The high-valent molybdenum (VI) N-heterocyclic carbene complexes,(NHC) MoO2 (1) and
(NHC) MoO (NtBu)(2)(NHC= 1, 3-bis (3, 5-di-tert-butyl-2-phenolato)-benzimidazol-2 …

In recent years, mesoionic carbenes (MICs) are finding increasing use as building blocks of
electro-and photoactive metal complexes. We present here a series of RuII and OsII …