The Brook rearrangement has emerged as one of the most pivotal transformations in organic
chemistry, with broad applications spanning organic synthesis, drug design, and materials …

The photoinduced ligand-to-metal charge transfer (LMCT) process has been extensively
investigated, however, the recovery of photocatalysts has remained a persistent challenge in …

The development of efficient methods for synthesizing β-silyl amines has long been a
significant goal in organic synthesis. Previous methods mainly relied on the use of …

Chiral 1, 3-amino alcohols are ubiquitous structural motifs in natural products and active
pharmaceutical ingredients. We present a highly enantioselective, inverse-electron-demand …

The aminocarbonylation of alkenes is an efficient approach to synthesize important β-amino
acid motifs. However, simple and convenient methods are still rare. Herein, we present a …

We report Cu-catalyzed enantioselective borylation/oxidation sequences that afford either
enantioenriched 1, 2-or 1, 3-amino alcohols starting from N, N-protected allylamines as a …

Nitrogen central radicals (NCRs) are versatile synthetic intermediates for creating functional
nitrogen-containing molecules. Herein, a photosensitized β-sulfonylamination of terminal …

The generation of long-chain alkoxy radicals via visible light-induced energy transfer (EnT)
has been accomplished through the design of a new class of bifunctional oxime esters …

Over the past decade, visible-light-mediated energy-transfer (EnT) catalysis, particularly
triplet–triplet energy-transfer (TTEnT) catalysis, has emerged as a mild and environmentally …

Aminoarenes are important molecules for broad applications in nearly all modern industries
that involve chemicals. Direct and site‐selective C− H bond amination of arenes provides …