Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

C Aubert, L Fensterbank, P Garcia, M Malacria… - Chemical …, 2011 - ACS Publications
Allenes have always fascinated chemists because of the intriguing features of the cumulated
diene function such as the higher reactivity compared to simple alkenes and the peculiar …

Cycloadditions and cyclizations of acetylenic, allenic, and conjugated dienyl sulfones

TG Back, KN Clary, D Gao - Chemical reviews, 2010 - ACS Publications
Sulfones display a diverse range of behavior and possess unique features that make them
valuable for numerous types of synthetic applications. As a result of their utility and …

Dendralenes Branch Out: Cross‐Conjugated Oligoenes Allow the Rapid Generation of Molecular Complexity

H Hopf, MS Sherburn - Angewandte Chemie International …, 2012 - Wiley Online Library
Twenty‐seven years ago, H. Hopf published the only previous comprehensive review on
branched oligoenes that had the title “Dendralenes: A Neglected Family of Hydrocarbons” …

[图书][B] Lithium compounds in organic synthesis: from fundamentals to applications

R Luisi, V Capriati - 2014 - books.google.com
This unique book covers fundamentals of organolithium compounds and gives a
comprehensive overview of the latest synthetic advances and developments in the field. Part …

Recent applications of chiral allenes in axial-to-central chirality transfer reactions

RK Neff, DE Frantz - Tetrahedron, 2015 - Elsevier
The unique structural architecture of the orthogonal cumulative π-system in allenes has
garnered the attention of synthetic chemists for over a century. 1 From a general reactivity …

Recent progress in the chemistry of allenes

HHAM Hassan - Current Organic Synthesis, 2007 - ingentaconnect.com
Allenes are important compounds in organic and synthetic organic chemistry and therefore a
large number of studies on their synthesis and reactions have been reported so far. We …

Thermal Cyclization of Phenylallenes That Contain ortho‐1,3‐Dioxolan‐2‐yl Groups: New Cascade Reactions Initiated by 1,5‐Hydride Shifts of Acetalic H Atoms

M Alajarin, B Bonillo, M Marin‐Luna… - … A European Journal, 2013 - Wiley Online Library
Abstract A series of 2‐(1, 3‐dioxolan‐2‐yl) phenylallenes that contained a range of
substituents (alkyl, aryl, phosphinyl, alkoxycarbonyl, sulfonyl) at the cumulenic C3 position …

Observation of new cycloisomerization pattern of 1, 5-bisallenes. catalyst and substituent effects

P Lu, S Ma - Organic Letters, 2007 - ACS Publications
In this paper a new cycloisomerization pattern of 1, 5-bisallenes based on the catalyst and
substituent effects has been reported. A range of seven-membered cross-conjugated trienes …

Rh-catalyzed triple allene approach to bicyclo [4.4. 0] decene derivatives and its application for the stepwise synthesis of steroid-like tetracyclic skeletons

P Lu, S Ma - Organic Letters, 2007 - ACS Publications
The construction of a new type of bicyclo [4.4. 0] decene products with a conjugated
exocyclic diene unit was developed using Rh-catalyzed cyclization of 1, 5-bisallenes in the …

Dendralene auf dem Vormarsch: kreuzkonjugierte Oligoene ermöglichen den schnellen Aufbau molekularer Komplexität

H Hopf, MS Sherburn - Angewandte Chemie, 2012 - Wiley Online Library
Vor 27 Jahren veröffentlichte H. Hopf den bisher einzigen umfassenden Übersichtsartikel zu
verzweigten Oligoenen mit dem Titel “Dendralene–eine vernachlässigte Gruppe …