High-valent iron (IV)–oxo complexes are of great significance as reactive intermediates
implicated in diverse chemical and biological systems. The aqueous iron (IV)–oxo complex …

Cyclic iron tetracarbenes are an emerging class of macrocyclic iron N-heterocyclic carbene
(NHC) complexes. They can be considered as an organometallic compound class inspired …

A nonradical oxidation-based peroxymonosulfate (PMS) activation is an attractive process
for pollutant elimination. Herein, a dual-metal-organic framework (MOF) assisted strategy to …

Sulphate radicals (SO 4 radical dot−) has been widely considered as the predominant active
species for pollutants degradation by the combination of ferrate (Fe (VI)) and …

Enzymes are highly efficient catalysts in Nature that often react with high stereo-, chemo-,
and regioselectivity. Usually, enzymes achieve this selectivity through substrate binding and …

Coordination engineering of high-valent Fe (IV)-oxo (FeIV= O) is expected to break the
activity-selectivity trade-off of traditional reactive oxygen species, while attempts to regulate …

Taurine/α‐ketoglutarate dioxygenase is an important enzyme that takes part in the cysteine
catabolism process in the human body and selectively hydroxylates taurine at the C1 …

The non‐heme iron ergothioneine synthase (EgtB) is a sulfoxide synthase that catalyzes
oxidative C− S bond formation in the synthesis of ergothioneine, which plays roles against …

Abstract Fe (II)/2‐oxoglutarate dependent dioxygenases (ODDs) share a double stranded
beta helix (DSBH) fold and utilise a common reactive intermediate, ferryl species, to catalyse …

High‐valent metal‐oxo species play critical roles in enzymatic catalysis yet their properties
are still poorly understood. In this work we report a combined experimental and …