Catalytic Upcycling of Polyolefins

J Sun, J Dong, L Gao, YQ Zhao, H Moon… - Chemical …, 2024 - ACS Publications
The large production volumes of commodity polyolefins (specifically, polyethylene,
polypropylene, polystyrene, and poly (vinyl chloride)), in conjunction with their low unit …

Chemical upcycling of polyolefin plastics using structurally well-defined catalysts

S Sun, W Huang - JACS Au, 2024 - ACS Publications
Single-use polyolefins are widely used in our daily life and industrial production due to their
light weight, low cost, superior stability, and durability. However, the rapid accumulation of …

Two mesoporous domains are better than one for catalytic deconstruction of polyolefins

A Tennakoon, X Wu, M Meirow, D Howell… - Journal of the …, 2023 - ACS Publications
Catalytic hydrogenolysis of polyolefins into valuable liquid, oil, or wax-like hydrocarbon
chains for second-life applications is typically accompanied by the hydrogen-wasting co …

Entropy confinement promotes hydrogenolysis activity for polyethylene upcycling

Q Kang, M Chu, P Xu, X Wang, S Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
Chemical upcycling that catalyzes waste plastics back to high‐purity chemicals holds great
promise in end‐of‐life plastics valorization. One of the main challenges in this process is the …

Influence of Pore Length on Hydrogenolysis of Polyethylene within a Mesoporous Support Architecture

M Meirow, A Tennakoon, X Wu, J Willmon… - The Journal of …, 2023 - ACS Publications
Due to the plastic waste crisis, selective chemical upcycling of polyolefins into value-added
products is a topic of intense interest, demanding polymer deconstruction processes that …

Size and Structure Effects of Carbon-Supported Ruthenium Nanoparticles on Waste Polypropylene Hydrogenolysis Activity, Selectivity, and Product Microstructure

JA Sun, PA Kots, ZR Hinton, NS Marinkovic, L Ma… - ACS …, 2024 - ACS Publications
Hydrogenolysis of plastic waste using Ru-based catalysts is promising for deconstructing
polyolefins into lower molecular weight products. Yet, the effect of catalyst atomic structure …

Review on Catalytic Depolymerization of Polyolefin Waste by Hydrogenolysis: State-of-the-Art and Outlook

A Musa, EA Jaseer, S Barman, N Garcia - Energy & Fuels, 2024 - ACS Publications
Mechanical recycling of plastic waste is not sustainable and inefficient in terms of the
resources needed to accomplish the process, and the quality of the materials obtained from …

Insight into the Competitive Adsorption Behavior of Polymer Chains in Silica Nanopores by Small-Angle Neutron Scattering

X Wang, X Lyu, X Wu, L He, JV Lamb, AS Filatov… - …, 2024 - ACS Publications
Processive hydrogenolysis catalysts, in which a metal nanoparticle (eg, Pt) embedded at the
bottom of a cylindrical silica nanopore can repeatedly cleave polymer chains and produce …

The Overlooked Potential of Sulfated Zirconia: Reexamining Solid Superacidity Toward the Controlled Depolymerization of Polyolefins

SR Cleary, AK Starace, CC Curran-Velasco… - Langmuir, 2024 - ACS Publications
Closed-loop recycling via an efficient chemical process can help alleviate the global plastic
waste crisis. However, conventional depolymerization methods for polyolefins, which …

Modulating the Contact Angle between Nonpolar Polymers and SiO2 Nanoparticles

A Majumder, AN Radzanowski, CY Wang, Y Mu… - …, 2024 - ACS Publications
Polymer–nanoparticle interactions play an important role in determining the morphology and
properties of polymer nanocomposites and controlling the polymeric reactions involving …