Cyclopropanes are common building blocks in pharmaceuticals, agrochemicals, and
organic materials. The most general methods for the synthesis of chiral cyclopropanes are …

The synthesis of dialkyl-substituted cyclopropanes is an important challenge in synthesis
with applications in drug discovery and agrochemistry. Herein, we report on the synthesis of …

Transition metal‐catalyzed carbene transfer reactions have a century‐old history in organic
chemistry and are a primary method for the synthesis of cyclopropanes. Much of the work in …

Small molecules containing 1, 1-dimethylcyclopropanes are prevalent throughout nature but
are difficult to synthesize using state-of-the-art metal-catalyzed carbene transfer methods …

Cyclopropanes are ubiquitous in medicines, yet robust synthetic access to a wide range of
sterically and electronically diverse analogs remains a challenge. To address the synthetic …

The cyclopropyl group is of great importance in medicinal chemistry, as it can be leveraged
to influence a range of pharmaceutical properties in drug molecules. This report describes a …

We report a novel visible light-mediated protocol for polychlorination of alkenes by
employing commercially available bulk chemicals, chloroform and chlorides. This …

Chiral cyclopropane derivatives are essential in synthetic chemistry and drug discovery.
Their synthesis commonly relies on asymmetric cyclopropanation of diazo compounds …

A radical mechanism enables simple and robust access to nonstabilized, alkyl iron carbenes
for novel (2+ 1) cycloadditions. This Fe-catalyzed strategy employs simple, aliphatic …

Intramolecular photoreactions of quinones can be interrupted by proton transfer using small
molecules, such as trimethylamine N-oxide. This interruption de-excites the reactive …