We present a wide-ranging interrogation of the border between single-molecule and solid-
state magnetism through a study of erbium-based Ising-type magnetic compounds with a …

Dipolar coupling is rarely invoked as a driving force for slow relaxation dynamics in
lanthanide-based single-molecule magnets, though it is often the strongest mechanism …

Magneto-structural correlations are of great importance in developing single-molecule
magnets (SMMs) for storage and quantum processing of information. In this work, three …

Single-molecule magnets (SMMs) are of interest for storage and quantum processing of
information. Herein, we report three new SMMs,([K (DME) 2][Er (COTTBS2) 2](1),[K (18-C …

The design of molecular magnets has progressed greatly by taking advantage of the ability
to impart successive perturbations and control vibronic transitions in 4f n systems through …

In recent years, the field of modern organometallic chemistry has witnessed interesting
developments with the cyclooctatetraenyl ligand (abbreviated with COT 2− or C 8 H 8 2−) …

Lanthanide complexes with judiciously designed ligands have been extensively studied for
their potential applications as single-molecule magnets. With the influence of ligands on …

The structure and magnetic properties of the bimetallic borohydride-bridged
dysprosocenium compound [{(η5-Cpttt)(η5-CpMe4t) Dy} 2 (μ: κ2: κ2-BH4)]+[B (C6F5) 4]−([3 …

The spin relaxation of an Er3+ tetranuclear single-molecule magnet,[Er (hdcCOT) I]
4,(hdcCOT= hexahydrodicyclopentacyclooctatetraenide dianion), is modeled as a near …

The potassium silole K2 [SiC4‐2, 5‐(SiMe3) 2‐3, 4‐Ph2] reacts with [M (η8‐COT)(THF)
4][BPh4](M= Er, Y; COT= cyclo‐octatetraenyl) in THF to give products that feature …