Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

C Papatriantafyllopoulou, EE Moushi… - Chemical Society …, 2016 - pubs.rsc.org
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry

A Escuer, J Esteban, SP Perlepes… - Coordination Chemistry …, 2014 - Elsevier
The chemistry of the azido-bridged coordination clusters continues to attract the intense
interest of synthetic inorganic chemists and scientists working in the interdisciplinary field of …

Controlled association of single-molecule magnets (SMMs) into coordination networks: towards a new generation of magnetic materials

IR Jeon, R Clérac - Dalton transactions, 2012 - pubs.rsc.org
The field of molecular magnetism has rapidly expanded since the discovery of single-
molecule magnets (SMMs) at the beginning of the 1990s. Numerous SMMs have been …

Cluster-based single-molecule magnets

CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Synthesis, Structure, and Optical‐response Magnetic Property of a Heteroarene‐azo Functionalized Mn19 Cluster

Y Deng, Y Wu, Z Li, Z Jagličić, RK Gupta… - Chinese Journal of …, 2023 - Wiley Online Library
Comprehensive Summary Metal clusters with photoswitching ligands can undergo magnetic
changes under light radiation, which makes them potential optical‐response magnetic …

[PDF][PDF] A [Mn-32] Double-Decker Wheel

M Manoli, R Inglis, MJ Manos… - Angewandte Chemie …, 2011 - research.ed.ac.uk
A mixed-valent [Mn32] cluster with a very rare" double-decker" wheel topology (see its metal-
oxygen core: MnIII, blue; MnII, pink; O, red) is reported. It is by far the highest nuclearity …

Inducing Single-Molecule Magnetism in a Family of Loop-of-Loops Aggregates: Heterometallic Mn40Na4 Clusters and the Homometallic Mn44 Analogue

EE Moushi, C Lampropoulos… - Journal of the …, 2010 - ACS Publications
The syntheses, crystal structures, and magnetic properties of a new family of heterometallic
Mn40Na4 and homometallic Mn44 loop-of-loops aggregates are reported. The reactions of …

Antiferromagnetic Porous Metal–Organic Framework Containing Mixed-Valence [MnII4MnIII24-O)2]10+ Units with Catecholase Activity and Selective Gas …

P Kar, R Haldar, CJ Gomez-Garcia… - Inorganic Chemistry, 2012 - ACS Publications
A multifunctional porous metal organic framework based on mixed-valence hexa-nuclear
[MnIII2MnII4O2 (pyz) 2 (C6H5CH2COO) 10](pyz= pyrazine) units has been synthesized. The …

Twisted molecular magnets

R Inglis, CJ Milios, LF Jones, S Piligkos… - Chemical …, 2012 - pubs.rsc.org
The use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of
a family of approximately fifty hexanuclear ([MnIII6]) and thirty trinuclear ([MnIII3]) Single …