Photoredox-mediated nickel-catalyzed cross-couplings have evolved as a new effective
strategy to forge carbon–heteroatom bonds that are difficult to access with traditional …

Abstract C (sp2)− N cross‐coupling is one of the most powerful transformations in organic
synthesis to construct highly ubiquitous anilines and aniline derivatives. The dominance of …

A nickel-catalyzed cross-coupling amination with weak nitrogen nucleophiles is described.
Aryl halides as well as aryl tosylates can be efficiently coupled with a series of weak N …

In recent years, mechanochemistry has become recognized as an efficient, practical, and
sustainable alternative for chemical synthesis. Adhering to the principles of green chemistry …

Herein, we report visible light‐promoted single nickel catalysis for diverse carbon–
heteroatom couplings under mild conditions. This mild, general, and robust method to …

Triarylamines are privileged core structures that are found in versatile optoelectronic
materials. New methods are constantly being sought for their preparation. Herein, a new …

The chemistry of nitrogen-containing heterocyclic compounds has been a multifaceted area
of research for an extended period due to their varied therapeutic and biological …

In this Letter, we report that the air-stable “naked nickel”[Ni (4-t Bustb) 3] is a competent
catalyst in thermal C–N bond formation between (hetero) aryl bromides and N-based …

A practical nickel-catalyzed C–N cross-coupling reaction between diarylamines and aryl
halides has been developed using commercially available NiCl2 (dppf) as the catalyst. This …

Nitrogen-containing heterocycles possessing N-alkenyl substituents are an important
structural motif. However, the synthetic methods reported thus far cannot selectively …