A review of semicarbazone-derived metal complexes for application in biomedicine and related fields

IA Mir, QU Ain, T Qadir, AQ Malik, S Jan… - Journal of Molecular …, 2024 - Elsevier
Semicarbazones are a type of chemical compound which are formed by the condensation
reaction of imines with aldehydes or ketones. These compounds are highly adaptable and …

Synthesis, crystal structure, Hirshfeld surface analysis, DFT, molecular docking and in vitro antitumor studies of (2E)-2-[4-(diethylamino) benzylidene]-N …

K Preetha, EB Seena, PK Maniyampara… - Journal of Molecular …, 2024 - Elsevier
The crystal structure and spectral characterization of a new proligand,(2E)-2-[4-
(diethylamino) benzylidene]-N-ethylhydrazinecarbothioamide is described. The compound …

Novel 2‐formylpyridine 4‐allyl‐S‐methylisothiosemicarbazone and Zn(II), Cu(II), Ni(II) and Co(III) complexes: Synthesis, characterization, crystal structure, antioxidant …

G Balan, O Burduniuc, I Usataia, V Graur… - Applied …, 2020 - Wiley Online Library
New zinc (II), copper (II), nickel (II) and cobalt (III) complexes,[Zn (HL) 2] I2 (1),[Cu (HL)
Cl2](2),[Cu (HL) Br2](3),[Cu (HL)(H2O) 2](ClO4) 2 (4),[Ni (HL) 2] I2· H2O (5),[Co (L) 2] Cl …

Novel cobalt complexes of pyridine-based NNS donor thiosemicarbazones: Synthesis, X-ray characterization, DFT calculations, Hirshfeld surface analysis, and …

PK Maniyampara, LK Suresh, K Jayakumar… - Journal of Molecular …, 2023 - Elsevier
Five novel cobalt complexes of pyridine-based heterocyclic thiosemicarbazones [Co (BpT)
2] Cl (1),[Co (BpT) 2](NO 3)·(H 2 O)(2),[Co (ApT) 2] Br·(CH 3 OH)(3),[Co (BpT) 2] Br (4) and …

Synthesis and characterisation of thiosemicarbazonato molybdenum (VI) complexes and their in vitro antitumor activity

V Vrdoljak, I Đilović, M Rubčić, SK Pavelić… - European journal of …, 2010 - Elsevier
New dioxomolybdenum (VI) complexes were obtained by the reaction of [MoO2 (acac) 2]
with thiosemicarbazone ligands derived from 3-thiosemicarbazide and 4-(diethylamino) …

Spectral, thermal and DFT studies of novel nickel (II) complexes of 2-benzoylpyridine-N4-methyl-3-thiosemicarbazone: crystal structure of a square planar azido-nickel …

K Jayakumar, EB Seena, MRP Kurup, S Kaya… - Journal of Molecular …, 2022 - Elsevier
Novel six Ni (II) complexes of an NNS donor 2-benzoylpyridine-N 4-methyl-3-
thiosemicarbazone (HL) are synthesized and characterized. Various physicochemical …

Copper (II) complexes as novel anticancer drug: Synthesis, spectral studies, crystal structures, in silico molecular docking and cytotoxicity

NA Mathews, MRP Kurup - Journal of Molecular Structure, 2022 - Elsevier
Three novel mixed ligand complexes of copper, derived from the parent
cyclohexylthiosemicarbazones were synthesized along with the secondary ligands such as …

In vitro biomolecular interaction studies and cytotoxic activities of copper (II) and zinc (II) complexes bearing ONS donor thiosemicarbazones

NA Mathews, MRP Kurup - Applied Organometallic Chemistry, 2021 - Wiley Online Library
Among all the bio‐metals, zinc and copper derivatives of ONS donor thiosemicarbazone
have aroused great interest because of their potential biological applications …

Synthesis, spectroscopy, electrochemistry, crystal structures and in vitro cytotoxicity of mononuclear molybdenum (VI) complexes incorporating tridentate ONO donor …

TM Asha, MRP Kurup - Inorganica Chimica Acta, 2018 - Elsevier
Four new mononuclear cis-dioxidomolybdenum (VI) complexes with the general formula
[MoO 2 LD], where H 2 L= tridentate aroylhydrazone and D= MeOH, pyridine (py), imidazole …

Synthesis, spectroscopic and crystal structure of nickel (II) complex of thiosemicarbazone basedSchiff base: Antimicrobial, anticancer and molecular docking studies

B Karpagam, M Sankarganesh, L Ravi… - Inorganic Chemistry …, 2021 - Elsevier
A new thiosemicarbazone based ligand synthesized by the facile condensation reaction of 3-
ethoxy salicylaldehyde and 4-phenylthiosemicarbazide. Ni (II) complex prepared by the …