Photophysics and photochemistry of 1, 2, 3-triazole-based complexes
The copper-catalysed cycloaddition of alkynes and azides to form 1, 2, 3-triazoles has
emerged as a powerful tool in ligand design and the synthesis of novel transition metal …
emerged as a powerful tool in ligand design and the synthesis of novel transition metal …
Complexation and extraction studies of trivalent actinides and lanthanides with water-soluble and CHON-compatible ligands for the selective extraction of americium
Novel hydrophilic ligands to selectively separate Am (III) are synthesized: 3, 3′-([2, 2′-
bipyridine]-6, 6′-diylbis (1 H-1, 2, 3-triazole-4, 1-diyl)) bis (propan-1-ol)(PrOH-BPTD) and 3 …
bipyridine]-6, 6′-diylbis (1 H-1, 2, 3-triazole-4, 1-diyl)) bis (propan-1-ol)(PrOH-BPTD) and 3 …
Theoretically unraveling the separation of Am (III)/Eu (III): insights from mixed N, O-donor ligands with variations of central heterocyclic moieties
QY Wu, YT Song, L Ji, CZ Wang, ZF Chai… - Physical Chemistry …, 2017 - pubs.rsc.org
With the fast development of nuclear energy, the issue related to spent nuclear fuel
reprocessing has been regarded as an imperative task, especially for the separation of …
reprocessing has been regarded as an imperative task, especially for the separation of …
Highly Efficient and Selective Dissolution Separation of Fission Products by an Ionic Liquid [Hbet][Tf2N]: A New Approach to Spent Nuclear Fuel Recycling
FL Fan, Z Qin, SW Cao, CM Tan, QG Huang… - Inorganic …, 2018 - ACS Publications
Here, we propose the use of carboxyl-functionalized ionic liquid,[Hbet][Tf2N], to separate the
fission products from spent nuclear fuels. This innovative method allows the selective …
fission products from spent nuclear fuels. This innovative method allows the selective …
Theoretical insights into preorganized pyridylpyrazole-based ligands toward the separation of Am (III)/Eu (III)
XH Kong, QY Wu, JH Lan, CZ Wang, ZF Chai… - Inorganic …, 2018 - ACS Publications
Pyridylpyrazole ligands have shown excellent competence for partitioning actinides from
lanthanides. As far as we know, the preorganization structure of the ligand has a great …
lanthanides. As far as we know, the preorganization structure of the ligand has a great …
Microwave-Assisted, Metal-and Azide-Free Synthesis of Functionalized Heteroaryl-1, 2, 3-triazoles via Oxidative Cyclization of N-Tosylhydrazones and Anilines
As the search for competent soft-Lewis basic complexants for separations continues to
evolve toward identification of a chemoselective moiety for speciation of the minor actinides …
evolve toward identification of a chemoselective moiety for speciation of the minor actinides …
Highly selective separation of actinides from lanthanides by dithiophosphinic acids: an in-depth investigation on extraction, complexation, and DFT calculations
To further reveal the extraction model for selective separation of trivalent actinides over
lanthanides by dithiophosphinic acids (DPAHs), five representative DPAH ligands with …
lanthanides by dithiophosphinic acids (DPAHs), five representative DPAH ligands with …
Selective complexation of trivalent americium over europium with substituted Triazolebipyridine-based ligand in high Level-Liquid Waste-A DFT Investigation
C Ebenezer, RV Solomon - Polyhedron, 2022 - Elsevier
Similar chemical properties like ionic radius and oxidation states exhibited by trivalent
actinides (An (III)) and lanthanides (Ln (III)) pose a challenge for their separation in …
actinides (An (III)) and lanthanides (Ln (III)) pose a challenge for their separation in …
Complexation of Actinide(III) and Lanthanide(III) with H4TPAEN for a Separation of Americium from Curium and Lanthanides
N Boubals, C Wagner, T Dumas, L Chanèac… - Inorganic …, 2017 - ACS Publications
Previous studies have identified the TPAEN ligand as a potentially appropriate complexing
agent in solvent extraction processes for the separation of americium (Am (III)) from the …
agent in solvent extraction processes for the separation of americium (Am (III)) from the …
Insight into the extraction mechanism of americium (III) over Europium (III) with pyridylpyrazole: a relativistic quantum chemistry study
XH Kong, QY Wu, CZ Wang, JH Lan… - The Journal of …, 2018 - ACS Publications
Separation of trivalent actinides (An (III)) and lanthanides (Ln (III)) is one of the most
important steps in spent nuclear fuel reprocessing. However, it is very difficult and …
important steps in spent nuclear fuel reprocessing. However, it is very difficult and …