Pillar-layered MOFs: functionality, interpenetration, flexibility and applications

F ZareKarizi, M Joharian, A Morsali - Journal of Materials Chemistry A, 2018 - pubs.rsc.org
Pillar-layered metal–organic frameworks (MOFs) are among the most interesting research
areas in crystalline materials. Due to the great number of reports related to pillar-layered …

Multi-dimensional metal-organic frameworks based on mixed linkers: Interplay between structural flexibility and functionality

S Bhattacharyya, TK Maji - Coordination Chemistry Reviews, 2022 - Elsevier
Metal-organic frameworks (MOFs) are regarded widely because of their intriguing structural
dynamism, which sets them apart from other porous materials. Such structural flexibility or …

Functionalization of metal–organic frameworks for photoactive materials

J Hao, X Xu, H Fei, L Li, B Yan - Advanced Materials, 2018 - Wiley Online Library
Metal–organic frameworks (MOFs) are intriguing platforms with multiple functionalities.
Additional functionalization of MOFs generates novel materials for various applications …

A multistimulus responsive porous coordination polymer: temperature-mediated control of solid-state [2+ 2] cycloaddition

IE Claassens, LJ Barbour… - Journal of the American …, 2019 - ACS Publications
Either of two different isomeric products can be selectively obtained by photochemical [2+ 2]
cycloaddition of 1, 4-bis [2-(4-pyridyl) ethenyl]-benzene within a porous coordination …

Cadmium (II) coordination polymers of 4-pyr-poly-2-ene and carboxylates: construction, structure, and photochemical double [2+ 2] cycloaddition and luminescent …

WJ Gong, ZG Ren, HX Li, JG Zhang… - Crystal Growth & …, 2017 - ACS Publications
Solvothermal reactions of Cd (NO3) 2· 4H2O with 4-pyr-poly-2-ene (ppene) in the presence
of benzene-1, 2-dicarboxylic acid (1, 2-H2BDC), benzene-1, 3-dicarboxylic acid (1, 3 …

[HTML][HTML] Spin-crossover modulation via single-crystal to single-crystal photochemical [2+ 2] reaction in Hofmann-type frameworks

LF Wang, WM Zhuang, GZ Huang, YC Chen… - Chemical …, 2019 - pubs.rsc.org
This study reports the first modulation of spin-crossover (SCO) behavior via a photochemical
[2+ 2] cycloaddition reaction. Here we construct two no-solvent Fe (II)–Ag (I) bimetallic …

Dynamic topochemical reaction tuned by guest molecules in the nanospace of a metal–organic framework

S Kusaka, A Kiyose, H Sato, Y Hijikata… - Journal of the …, 2019 - ACS Publications
Reaction in well-designed solids allows yielding products with high selectivity and unique
compounds that cannot be obtained in solution. However, the precise tuning of the …

[HTML][HTML] CO 2-induced single-crystal to single-crystal transformations of an interpenetrated flexible MOF explained by in situ crystallographic analysis and molecular …

A Hazra, DP van Heerden, S Sanyal, P Lama… - Chemical …, 2019 - pubs.rsc.org
A molecular-level investigation is reported on breathing behaviour of a metal–organic
framework (1) in response to CO2 gas pressure. High-pressure gas adsorption shows a …

Solvent‐Mediated Synthesis of Cyclobutane Isomers in a Photoactive Cadmium (II) Porous Coordination Polymer

IE Claassens, VI Nikolayenko… - Angewandte Chemie …, 2018 - Wiley Online Library
Abstract Photochemical [2+ 2] cycloaddition of 1, 4‐bis [2‐(4‐pyridyl) ethenyl] benzene,
carried out in a CdII porous coordination polymer (PCP), produces different isomeric …

Turning flexibility into rigidity: stepwise locking of interpenetrating networks in a MOF crystal through click reaction

D Jedrzejowski, M Pander, W Nitek, W Bury… - Chemistry of …, 2021 - ACS Publications
Post-synthetic modifications of metal–organic frameworks (MOFs) enable synthesis of
materials with enhanced performance characteristics or those inaccessible by direct …