Intramolecular cross-linking methodologies for the synthesis of polymer nanoparticles

S Mavila, O Eivgi, I Berkovich, NG Lemcoff - Chemical reviews, 2016 - ACS Publications
The advancement of polymer science embraces the invention of molecular constructs that
provide functional applications. As a result, the development of novel methodologies for the …

The Sonogashira reaction: a booming methodology in synthetic organic chemistry

R Chinchilla, C Nájera - Chemical reviews, 2007 - ACS Publications
The array of transition-metal-catalyzed cross-coupling reactions can easily be considered
nowadays cornerstones in the field of organic synthesis. 1, 2 Among them, the palladium …

Highly contorted superhelicene hits near-infrared circularly polarized luminescence

S Míguez-Lago, IFA Mariz, MA Medel, JM Cuerva… - Chemical …, 2022 - pubs.rsc.org
Herein we describe a novel superhelicene structure consisting of three hexa-peri-
hexabenzocoronene (HBC) units arranged in a helical geometry and creating two carbo [5] …

Palladium‐based catalytic systems for the synthesis of conjugated enynes by Sonogashira reactions and related alkynylations

H Doucet, JC Hierso - Angewandte Chemie International …, 2007 - Wiley Online Library
Conjugated alkynes are recurring building blocks in natural products, a wide range of
industrial intermediates, pharmaceuticals and agrochemicals, and molecular materials for …

Pyrrole Synthesis via Allylic sp3 C−H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes

S Rakshit, FW Patureau, F Glorius - Journal of the American …, 2010 - ACS Publications
A conceptually novel pyrrole synthesis is reported, efficiently merging enamines and
(unactivated) alkynes under oxidative conditions. In an intermolecular Rh catalyzed process …

Designed synthesis of atom-economical Pd/Ni bimetallic nanoparticle-based catalysts for sonogashira coupling reactions

SU Son, Y Jang, J Park, HB Na, HM Park… - Journal of the …, 2004 - ACS Publications
Designed Synthesis of Atom-Economical Pd/Ni Bimetallic Nanoparticle-Based Catalysts for
Sonogashira Coupling Reactions | Journal of the American Chemical Society ACS ACS …

Conformational control of Pd 2 L 4 assemblies with unsymmetrical ligands

JEM Lewis, A Tarzia, AJP White, KE Jelfs - Chemical Science, 2020 - pubs.rsc.org
With increasing interest in the potential utility of metallo-supramolecular architectures for
applications as diverse as catalysis and drug delivery, the ability to develop more complex …

Palladium-catalyzed intermolecular decarboxylative coupling of 2-phenylbenzoic acids with alkynes via C− H and C− C bond activation

C Wang, S Rakshit, F Glorius - Journal of the American Chemical …, 2010 - ACS Publications
A novel protocol for palladium-catalyzed intermolecular formal [4+ 2] annulation of 2-
phenylbenzoic acids with alkynes is described. Acridine is shown to be essential for the high …

Influence of Alkyl Substituents on the Solution- and Surface-Organization of Hexa-peri-hexabenzocoronenes

M Kastler, W Pisula, D Wasserfallen… - Journal of the …, 2005 - ACS Publications
Three hexa-peri-hexabenzocoronenes (HBCs) with branched, bulky alkyl substituents of
different lengths in the periphery of the aromatic core have been synthesized to tune the self …

Selective synthesis of indoles by cobalt (III)-catalyzed C–H/N–O functionalization with nitrones

H Wang, M Moselage, MJ Gonzalez… - ACS Catalysis, 2016 - ACS Publications
The redox-neutral annulation of alkynes by differently decorated nitrones set the stage for a
step-economical access to indoles with ample substrate scope. The redox-neutral C–H/N–O …