Magnetic anisotropies in paramagnetic polynuclear metal complexes
M Nakano, H Oshio - Chemical Society Reviews, 2011 - pubs.rsc.org
The study of the magnetic properties of highly anisotropic paramagnetic molecules is an
area of intense current research interest. Of these, single-molecule magnets (SMMs) and …
area of intense current research interest. Of these, single-molecule magnets (SMMs) and …
Beyond the spin model: exchange coupling in molecular magnets with unquenched orbital angular momenta
In this critical review we review the problem of exchange interactions in polynuclear metal
complexes involving orbitally degenerate metal ions. The key feature of these systems is …
complexes involving orbitally degenerate metal ions. The key feature of these systems is …
Trigonal-Bipyramidal metal cyanide complexes: A versatile platform for the systematic assessment of the magnetic properties of prussian blue materials
KE Funck, MG Hilfiger, CP Berlinguette… - Inorganic …, 2009 - ACS Publications
Pentanuclear cyanide-bridged clusters of the general formula {[M (tmphen) 2] 3 [M′(CN) 6]
2}(tmphen= 3, 4, 7, 8-tetramethyl-1, 10-phenanthroline) have been under investigation in our …
2}(tmphen= 3, 4, 7, 8-tetramethyl-1, 10-phenanthroline) have been under investigation in our …
Enhancing the Blocking Temperature in Single‐Molecule Magnets by Incorporating 3d–5d Exchange Interactions
KS Pedersen, M Schau‐Magnussen… - … A European Journal, 2010 - Wiley Online Library
We report the first single‐molecule magnet (SMM) to incorporate the Os (CN) 6 3− moiety.
The compound (1) has a trimeric, cyanide‐bridged MnIII‐OsIII‐MnIII skeleton in which MnIII …
The compound (1) has a trimeric, cyanide‐bridged MnIII‐OsIII‐MnIII skeleton in which MnIII …
Synthesis, Structure, and Magnetic Properties of 1D {[MnIII(CN)6][MnII(dapsc)]}n Coordination Polymers: Origin of Unconventional Single-Chain Magnet Behavior
VD Sasnovskaya, VA Kopotkov, AD Talantsev… - Inorganic …, 2017 - ACS Publications
Two one-dimensional cyano-bridged coordination polymers, namely,{[MnII (dapsc)][MnIII
(CN) 6][K (H2O) 2.75 (MeOH) 0.5]} n· 0.5 n (H2O)(I) and {[MnII (dapsc)][MnIII (CN) 6][K (H2O) …
(CN) 6][K (H2O) 2.75 (MeOH) 0.5]} n· 0.5 n (H2O)(I) and {[MnII (dapsc)][MnIII (CN) 6][K (H2O) …
Magnetic exchange between metal ions with unquenched orbital angular momenta: basic concepts and relevance to molecular magnetism
A Palii, B Tsukerblat, JM Clemente-Juan… - … Reviews in Physical …, 2010 - Taylor & Francis
This review article is a first attempt to give a systematic and comprehensive description (in
the framework of the unified theoretical approach) of the exchange interactions in …
the framework of the unified theoretical approach) of the exchange interactions in …
Combined Ligand Field and Density Functional Theory Analysis of the Magnetic Anisotropy in Oligonuclear Complexes Based on FeIII−CN−MII Exchange-Coupled …
M Atanasov, P Comba, CA Daul - Inorganic chemistry, 2008 - ACS Publications
Magnetic anisotropy in cyanide-bridged single-molecule magnets (SMMs) with FeIII− CN−
MII (M= Cu, Ni) exchange-coupled pairs was analyzed using a density functional theory …
MII (M= Cu, Ni) exchange-coupled pairs was analyzed using a density functional theory …
Role of orbital degeneracy in the single molecule magnet behavior of a mononuclear high-spin Fe (II) complex
AV Palii, JM Clemente-Juan, E Coronado… - Inorganic …, 2010 - ACS Publications
To explain the single-molecule magnet behavior of the mononuclear complex [(tpaMes) Fe]−
we have developed a model that takes into account the trigonal ligand field splitting of the …
we have developed a model that takes into account the trigonal ligand field splitting of the …
Single-Ion Anisotropy and Exchange Interactions in the Cyano-Bridged Trimers MnIII2MIII(CN)6 (MIII = Co, Cr, Fe) Species Incorporating [Mn(5-Brsalen)]+ Units …
PLW Tregenna-Piggott, D Sheptyakov, L Keller… - Inorganic …, 2009 - ACS Publications
The electronic structures of the compounds K [(5-Brsalen) 2 (H2O) 2-Mn2MIII (CN) 6]· 2H2O
(MIII= CoIII, CrIII, FeIII) have been determined by inelastic neutron scattering (INS) and …
(MIII= CoIII, CrIII, FeIII) have been determined by inelastic neutron scattering (INS) and …
Trinuclear {M1}CN{M2}2 Complexes (M1 = CrIII, FeIII, CoIII; M2 = CuII, NiII, MnII). Are Single Molecule Magnets Predictable?
The reaction of the hexacyanometalates K3 [M1 (CN) 6](M1= CrIII, FeIII, CoIII) with the
bispidine complexes [M2 (L1)(X)] n+ and [M2 (L2)(X)] n+(M2= MnII, NiII, CuII; L1= 3-methyl-9 …
bispidine complexes [M2 (L1)(X)] n+ and [M2 (L2)(X)] n+(M2= MnII, NiII, CuII; L1= 3-methyl-9 …