Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Photobiocatalysis: activating redox enzymes by direct or indirect transfer of photoinduced electrons

SH Lee, DS Choi, SK Kuk… - Angewandte Chemie …, 2018 - Wiley Online Library
Biocatalytic transformation has received increasing attention in the green synthesis of
chemicals because of the diversity of enzymes, their high catalytic activities and specificities …

Cofactor NAD (P) H regeneration inspired by heterogeneous pathways

X Wang, T Saba, HHP Yiu, RF Howe, JA Anderson… - Chem, 2017 - cell.com
Biocatalysis can empower chemical, pharmaceutical, and energy industries, where the use
of enzymes facilitates low-energy, sustainable methods of producing high-value chemicals …

Enzymatic reductions for the chemist

F Hollmann, IWCE Arends, D Holtmann - Green Chemistry, 2011 - pubs.rsc.org
When challenged by a difficult reduction reaction, a chemist should always also consider
biocatalysis in synthesis planning. The inherent selectivity of enzymes has been known for …

[图书][B] Organic electrochemistry

O Hammerich, B Speiser - 2016 - api.taylorfrancis.com
Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

Synthetic cascades are enabled by combining biocatalysts with artificial metalloenzymes

V Köhler, YM Wilson, M Dürrenberger, D Ghislieri… - Nature Chemistry, 2013 - nature.com
Enzymatic catalysis and homogeneous catalysis offer complementary means to address
synthetic challenges, both in chemistry and in biology. Despite its attractiveness, the …

Enzymatic carbon dioxide to formate: mechanisms, challenges and opportunities

H Chen, Y Huang, C Sha, JM Moradian… - … and Sustainable Energy …, 2023 - Elsevier
The reduction of carbon dioxide (CO 2) gas into soluble formate is one of the most promising
carbon neutralization strategies since it facilitates simultaneous fixation of carbon dioxide …

Multistep one-pot reactions combining biocatalysts and chemical catalysts for asymmetric synthesis

CA Denard, JF Hartwig, H Zhao - ACS catalysis, 2013 - ACS Publications
In a continuous effort to emulate the efficiency of biosynthetic pathways, considerable
progress has been made in developing one-pot chemoenzymatic processes that take full …

[PDF][PDF] How Green is Biocatalysis? To Calculate is To Know.

Y Ni, D Holtmann, F Hollmann - ChemCatChem, 2014 - researchgate.net
Green chemistry aims to minimize the environmental hazards of chemical processes and
their products. Ever since its introduction by Anastas,[1] this principle has inspired …

Biocatalytic redox reactions for organic synthesis: nonconventional regeneration methods

F Hollmann, IWCE Arends, K Buehler - ChemCatChem, 2010 - Wiley Online Library
Redox enzymes have tremendous potential as catalysts for preparative organic chemistry.
Their usually high selectivity, paired with their catalytic efficiency under mild reaction …