Transition metal chemistry of cyclopropenes and cyclopropanes

M Rubin, M Rubina, V Gevorgyan - Chemical reviews, 2007 - ACS Publications
Three-membered carbocycles are extremely important versatile building blocks for organic
chemistry. Their unique structural and electronic properties give rise to an array of very …

Functionalized fullerenes in water. The first 10 years of their chemistry, biology, and nanoscience

E Nakamura, H Isobe - Accounts of chemical research, 2003 - ACS Publications
Fullerenes are entirely insoluble in water, but suitable functionalization makes the molecules
soluble. Studies on water-soluble fullerene derivatives led to the discovery of the interaction …

A ring expansion strategy towards diverse azaheterocycles

R Li, B Li, H Zhang, CW Ju, Y Qin, XS Xue, D Zhao - Nature Chemistry, 2021 - nature.com
The development of innovative strategies for the synthesis of N-heterocyclic compounds is
an important topic in organic synthesis. Ring expansion methods to form large N …

Recent developments of cyclopropene chemistry

ZB Zhu, Y Wei, M Shi - Chemical Society Reviews, 2011 - pubs.rsc.org
This critical review discusses recent developments in the field of cyclopropene chemistry.
Although several excellent reviews that mainly focused on the thermolysis and pyrolysis as …

Cobalt‐Catalyzed Facial‐Selective Hydroalkylation of Cyclopropenes

ZL Zhang, Z Li, YT Xu, L Yu, J Kuang, Y Li… - Angewandte …, 2023 - Wiley Online Library
Cyclopropene hydrofunctionalization has been a promising strategy for accessing multi‐
substituted cyclopropanes; however, cyclopropene hydroalkylation remains …

Copper-catalyzed diastereo-and enantioselective desymmetrization of cyclopropenes: Synthesis of cyclopropylboronates

A Parra, L Amenos, M Guisan-Ceinos… - Journal of the …, 2014 - ACS Publications
A novel Cu-catalyzed diastereo-and enantioselective desymmetrization of cyclopropenes to
afford nonracemic cyclopropylboronates is described. Trapping the cyclopropylcopper …

Recent developments in cyclopropene chemistry

P Li, X Zhang, M Shi - Chemical Communications, 2020 - pubs.rsc.org
The transformations of cyclopropenes have attracted the attention of organic chemists for
decades. As readily accessible strained carbocycles, cyclopropenes show a diverse range …

Copper mediated carbometalation reactions

DS Müller, I Marek - Chemical Society Reviews, 2016 - pubs.rsc.org
Since the first discovery of carbocupration of alkynes in the 1970s a tremendous amount of
research has been carried out in this field. The exceptionally high selectivities obtained …

Strained small rings in gold-catalyzed rapid chemical transformations

BL Lu, L Dai, M Shi - Chemical Society Reviews, 2012 - pubs.rsc.org
Gold-catalyzed reactions, which have been widely explored over the past several years, are
powerful tools in organic synthesis to access complex molecular frameworks, and some …

Nitrone Directing Groups in Rhodium (III)‐Catalyzed C− H Activation of Arenes: 1, 3‐Dipoles versus Traceless Directing Groups

F Xie, S Yu, Z Qi, X Li - Angewandte Chemie International …, 2016 - Wiley Online Library
Functionalizable directing groups (DGs) are highly desirable in C− H activation chemistry.
The nitrone DGs are explored in rhodium (III)‐catalyzed C− H activation of arenes and …