Carbon–carbon bond formation by [3, 3]-sigmatropic rearrangement is a fundamental and
powerful method that has been used to build organic molecules for a long time. Initially …

This review is dedicated to the different varieties of macrocycles synthesis bearing indole
units in their architecture by metal-catalyzed strategies. The progress of the new …

Benzofurans, 2H‐chromenes and benzoxepines are key structural elements present in
several natural products and pharmaceuticals. Here, we describe an easy‐to‐execute …

In this report, we compiled various strategies involving a ring-rearrangement metathesis as a
key step to assemble diverse molecules. Popular name reactions such as Grignard reaction …

Catalysts for Claisen rearrangement have been intensively studied to overcome the need for
high temperature. However, previous studies have encountered challenges, such as the …

This review summarizes various strategies that combine metathesis with diverse named and
unnamed reactions to create molecular diversity in producing carbocycles, macrocycles, and …

Propargyl aza-Claisen rearrangement of 4-propargylaminoisoxazoles 1 proceeded in the
presence of cationic gold (I) catalysts to give 4-amino-5-allenylisoxazoles 2 in good to high …

An auxiliary-based protocol is described for an asymmetric allenoate Claisen
rearrangement. Silicated tosic acid (10 mol%) was used as an inexpensive, user-friendly …

Herein, we summarize the synthetic approaches that have been developed for the synthesis
of star‐shaped molecules. Typically, to design such highly functionalized molecules, simple …

A simple and effective protocol for synthesizing dihydrooxepinobenzofuranone derivatives
was developed using Claisen Rearrangement (CR) and Ring Closing Metathesis (RCM) …