Enzyme Immobilization using Covalent Organic Frameworks: From Synthetic Strategy to COFs Functional Role

X Fan, S Zhai, S Xue, L Zhi - ACS Applied Materials & Interfaces, 2024 - ACS Publications
Enzymes, a class of biocatalysts, exhibit remarkable catalytic efficiency, specificity, and
selectivity, governing many reactions that are essential for various cascades within living …

Covalent organic frameworks for the purification of recombinant enzymes and heterogeneous biocatalysis

S Paul, M Gupta, A Kumar Mahato… - Journal of the …, 2023 - ACS Publications
Recombinant enzymes have gained prominence due to their diverse functionalities and
specificity and are often a greener alternative in biocatalysis. This context makes purifying …

Incorporation of enzyme-mimic species in porous materials for the construction of porous biomimetic catalysts

Z Liu, JL Ling, YY Liu, BH Zheng, CD Wu - Chemical Communications, 2024 - pubs.rsc.org
The unique catalytic properties of natural enzymes have inspired chemists to develop
biomimetic catalyst platforms for the intention of retaining the unique functions and solving …

Improving the Bioactivity and Stability of Embedded Enzymes by Covalent Organic Frameworks

WJ Li, YM Li, H Ren, CY Ji, L Cheng - ACS Applied Materials & …, 2023 - ACS Publications
De novo embedding enzymes within reticular chemistry materials have shown the
enhancement of physical and chemical stability for versatile catalytic reactions. Compared to …

Responsive multi‐arm PEG‐modified COF nanocomposites: Dynamic photothermal, pH/ROS dual‐responsive, targeted carriers for rheumatoid arthritis treatment

S Ge, X Wang, X Zhao, L Yuan, X Bao… - Advanced …, 2024 - Wiley Online Library
Rheumatoid arthritis (RA) is a chronic immune disease characterized by the infiltration of
immune cells and the proliferation of fibroblast‐like synoviocytes (FLS) at the joint site …

Nanostructurally Engineering Covalent Organic Frameworks for Boosting CO2 Photoreduction

T Zheng, X Ding, T Sun, X Yang, X Wang, X Zhou… - Small, 2024 - Wiley Online Library
Herein, a series of imine‐linked covalent organic frameworks (COFs) are developed with
advanced ordered mesoporous hollow spherical nanomorphology and ultra‐large …

Pore-interface engineering improves doxorubicin loading to triazine-based covalent organic framework

P Rathi, S Chowdhury, PP Das, AK Keshri… - Materials …, 2024 - pubs.rsc.org
High drug-loading capacity is the most advantageous property of porous nanocarriers for
cancer therapy. Covalent organic frameworks (COFs) are a novel class of porous …

Metal–Organic Framework‐Induced Rh Monocoodination on Diphosphine Ligand Enables Catalytic Hydroformylation of Aliphatic Olefins at Room Temperature and …

Z Zheng, M Sun, X Zhao, W Zhang, H Jiang… - Angewandte …, 2024 - Wiley Online Library
Persistent challenges in hydroformylation of olefins include controlling regioselectivity,
particularly for short aliphatic olefins and conducting reactions under ambient conditions. We …

Enhancing the Crystallinity of Keto‐enamine‐Linked Covalent Organic Frameworks through an in situ Protection‐Deprotection Strategy

K Koner, S Mohata, Y Ogaeri… - Angewandte Chemie …, 2024 - Wiley Online Library
Abstract β‐Keto‐enamine‐linked 2D covalent organic frameworks (COFs) have emerged as
highly robust materials, showing significant potential for practical applications. However, the …

Enhancing photocatalytic performance of covalent organic frameworks via ionic polarization

J Zhang, X Li, H Hu, H Huang, H Li, X Sun… - Nature …, 2024 - nature.com
Covalent organic frameworks have emerged as a thriving family in the realm of
photocatalysis recently, yet with concerns about their high exciton dissociation energy and …