Applications of oxazolidinones as chiral auxiliaries in the asymmetric alkylation reaction applied to total synthesis

MM Heravi, V Zadsirjan, B Farajpour - RSC advances, 2016 - pubs.rsc.org
Various chiral oxazolidinones (Evans' oxazolidinones) have been employed as effective
chiral auxiliaries in the asymmetric alkylation of different enolates. This strategy has been …

Chiral methyl-branched pheromones

T Ando, R Yamakawa - Natural product reports, 2015 - pubs.rsc.org
Covering: up to October 2014 Insect pheromones are some of the most interesting natural
products because they are utilized for interspecific communication between various insects …

Preparation of Optically Enriched Secondary Alkyllithium and Alkylcopper Reagents—Synthesis of (−)‐Lardolure and Siphonarienal

V Morozova, J Skotnitzki, K Moriya… - Angewandte Chemie …, 2018 - Wiley Online Library
Optically enriched secondary alkyl iodides were converted into secondary alkyllithium and
secondary alkylcopper compounds with very high retention of configuration. Quenching with …

Stereoselective Preparation and Reactions of Chiral Secondary Alkyllithiums

J Skotnitzki, A Kremsmair, P Knochel - Synthesis, 2020 - thieme-connect.com
The preparation of chiral non-stabilized open-chain alkyllithium reagents prepared from the
corresponding chiral secondary alkyl iodides and their subsequent transmetalation to the …

Concise synthesis of reduced propionates by stereoselective reductions combined with the Kobayashi reaction

T Nakamura, M Harachi, T Kano, Y Mukaeda… - Organic …, 2013 - ACS Publications
A concise and straightforward synthesis of 2, 4, 6-trimethyloctanoates was established by
using the sequence of the vinylogous Mukaiyama aldol reaction and regio-and …

Herstellung enantiomerenangereicherter sekundärer Alkyllithium‐und Alkylkupferverbindungen–Synthese von (−)‐Lardolure und Siphonarienal

V Morozova, J Skotnitzki, K Moriya… - Angewandte …, 2018 - Wiley Online Library
Enantiomerenangereicherte sekundäre Alkyliodide wurden in sekundäre Alkyllithium‐und
Alkylkupferverbindungen unter hoher Retention der Konfiguration überführt …

Strategies for the Synthesis of Deoxypropionates

F Schmid, A Baro, S Laschat - Synthesis, 2017 - thieme-connect.com
Deoxypropionates constitute an important class of polyketide natural products. The
biological properties of deoxypropionates are diverse and synthetic strategies toward their …

手性甲基脂肪烃类昆虫信息素的合成研究进展

袁谷城, 边庆花, 王敏, 钟江春 - 有机化学, 2021 - sioc-journal.cn
摘要手性甲基脂肪烃类昆虫信息素包括单手性甲基, 双手性甲基和多手性甲基脂肪烃类昆虫信息
素, 在棘翅夜蛾, 南部云杉天牛, 桃潜叶蛾等多种农林害虫的绿色防控领域具有极具发展的前景 …

Total Synthesis of (−)‐Magnoshinin and (+)‐Merrilliaquinone: Application of a Late‐Stage Oxidative Functionalization Protocol

A Salam, D Kumar, TK Sahu, R Khan… - European Journal of …, 2022 - Wiley Online Library
A unified approach for the first enantioselective total synthesis of magnoshinin and
merrilliaquinone is reported. The key feature of the synthesis is the DDQ assisted …

[PDF][PDF] Synthesis of deoxypropionates using a combination of enzymatic desymmetrisation and substrate controlled conjugate addition

G Le Calvez, MD Witte, AJ Minnaard - Beilstein Archives, 2024 - beilstein-journals.org
The all-syn deoxypropionate motif can be efficiently constructed using a combination of
enzymatic desymmetrization and substrate-controlled conjugate addition of lithium …