On the nature of the active species in palladium catalyzed Mizoroki–Heck and Suzuki–Miyaura couplings–homogeneous or heterogeneous catalysis, a critical review

NTS Phan, M Van Der Sluys… - Advanced Synthesis & …, 2006 - Wiley Online Library
A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki
coupling reactions over the last 15 years. Historically, nearly every form of palladium used …

The potential of palladacycles: more than just precatalysts

J Dupont, CS Consorti, J Spencer - Chemical Reviews, 2005 - ACS Publications
The past half century has witnessed enormous growth in transition-metal organometallic
chemistry, both as a scientific discipline and as a subject for research and applications in …

Modified (NHC)Pd(allyl)Cl (NHC = N-Heterocyclic Carbene) Complexes for Room-Temperature Suzuki−Miyaura and Buchwald−Hartwig Reactions

N Marion, O Navarro, J Mei, ED Stevens… - Journal of the …, 2006 - ACS Publications
A series of (NHC) Pd (R-allyl) Cl complexes [NHC: IPr= N, N '-bis (2, 6-diisopropylphenyl)
imidazol-2-ylidene, SIPr= N, N '-bis (2, 6-diisopropylphenyl)-4, 5-dihydroimidazol-2-ylidene; …

Palladium-catalyzed micellar cross-couplings: An outlook

TN Ansari, F Gallou, S Handa - Coordination Chemistry Reviews, 2023 - Elsevier
In the last decades, cross-coupling approaches have been widely used to generate
structural diversity efficiently. Among various transition-metals, palladium has remained the …

Fast, easy, clean chemistry by using water as a solvent and microwave heating: the Suzuki coupling as an illustration

NE Leadbeater - Chemical Communications, 2005 - pubs.rsc.org
Water is an excellent solvent for organic chemistry and microwave heating offers a very
efficient way of heating reaction mixtures. In this article, by focusing on the Suzuki reaction, it …

Phosphine-free palladium acetate catalyzed Suzuki reaction in water

L Liu, Y Zhang, Y Wang - The Journal of organic chemistry, 2005 - ACS Publications
Pd (OAc) 2 in a mixture of water and poly (ethylene glycol)(PEG) is shown to be an
extremely active catalyst for the Suzuki reaction of aryl iodides and bromides. The reaction …

Organic reactions in low melting mixtures based on carbohydrates and l-carnitine—a comparison

F Ilgen, B König - Green Chemistry, 2009 - pubs.rsc.org
A new L-carnitine/urea melt was developed and compared to previously reported sugar and
sugar alcohol melts using several organic reactions for benchmarking. Physicochemical …

Synthesis of Noble Metal Nanoparticles Embedded in the Shell Layer of Core−Shell Poly(styrene-co-4-vinylpyridine) Micospheres and Their Application in Catalysis

F Wen, W Zhang, G Wei, Y Wang, J Zhang… - Chemistry of …, 2008 - ACS Publications
The noble metal nanoparticles of Pd, Au, and Ag embedded in the shell layer of core− shell
poly (styrene-co-4-vinylpyridine) micospheres were synthesized, and the catalytic activity of …

Formation and role of palladium chalcogenide and other species in Suzuki–Miyaura and Heck C–C coupling reactions catalyzed with palladium (II) complexes of …

A Kumar, GK Rao, S Kumar, AK Singh - Organometallics, 2014 - ACS Publications
Palladium (II) complexes of organochalcogen ligands have emerged as viable alternatives
to complexes of phosphine/carbene ligands for Suzuki–Miyaura and Heck C–C cross …

Palladacycle containing nitrogen and selenium: highly active pre-catalyst for the Suzuki–Miyaura coupling reaction and unprecedented conversion into nano-sized …

GK Rao, A Kumar, J Ahmed, AK Singh - Chemical communications, 2010 - pubs.rsc.org
Newly synthesized, air and moisture insensitive palladacycle [PdCl (L–H)](L=(C6H5)(2-
HOC6H4) CHNH (CH2) 3SePh; a (N, Se, C−) ligand) shows high catalytic activity for the …