Alternative catalytic materials: carbides, nitrides, phosphides and amorphous boron alloys

AM Alexander, JSJ Hargreaves - Chemical Society Reviews, 2010 - pubs.rsc.org
Catalysts generated by the addition of carbon, nitrogen or phosphorus to transition metals
have interesting properties and potential applications. The addition of carbon, nitrogen or …

Heterogeneous catalytic hydrogenation reactions in continuous‐flow reactors

M Irfan, TN Glasnov, CO Kappe - ChemSusChem, 2011 - Wiley Online Library
Microreactor technology and continuous flow processing in general are key features in
making organic synthesis both more economical and environmentally friendly …

Metal and metal oxide supported on ordered mesoporous carbon as heterogeneous catalysts

M Gao, L Wang, Y Yang, Y Sun, X Zhao, Y Wan - ACS Catalysis, 2023 - ACS Publications
The evolution of model catalyst systems has experienced single-crystal surfaces of different
transition metals and different crystal faces, two-dimensional systems with nanoparticles …

Breaking scaling relationships in alkynol semi-hydrogenation by manipulating interstitial atoms in Pd with d-electron gain

Y Yang, X Zhu, L Wang, J Lang, G Yao, T Qin… - Nature …, 2022 - nature.com
Pd catalysts are widely used in alkynol semi-hydrogenation. However, due to the existence
of scaling relationships of adsorption energies between the key adsorbed species, the …

Transition metal silicides: fundamentals, preparation and catalytic applications

X Chen, C Liang - Catalysis Science & Technology, 2019 - pubs.rsc.org
Transition metal silicides as typical intermetallic compounds are important in
microelectronics and ceramics because of their good electrical conductivity, high chemical …

A critical look at reactions in class I and II gas-expanded liquids using CO2 and other gases

GR Akien, M Poliakoff - Green Chemistry, 2009 - pubs.rsc.org
A critical look at reactions in class I and II gas-expanded liquids using CO2 and other gases -
Green Chemistry (RSC Publishing) DOI:10.1039/B904097H Royal Society of Chemistry View …

Supercritical fluids in catalysis: opportunities of in situ spectroscopic studies and monitoring phase behavior

JD Grunwaldt, R Wandeler, A Baiker - Catalysis Reviews, 2003 - Taylor & Francis
A number of homogeneous and heterogeneous catalytic reactions have been successfully
performed in supercritical fluids (SCFs). An overview on recent developments in the areas of …

In situ spectroscopic investigation of heterogeneous catalysts and reaction media at high pressure

JD Grunwaldt, A Baiker - Physical Chemistry Chemical Physics, 2005 - pubs.rsc.org
In situ characterization of catalysts by means of complementary spectroscopic techniques
can be regarded as the first step towards rational catalyst design. Spurred by the growing …

How to increase the selectivity of Pd-based catalyst in alkynol hydrogenation: Effect of second metal

A Yarulin, I Yuranov, F Cárdenas-Lizana… - Applied Catalysis A …, 2014 - Elsevier
The development of selective Pd-based catalyst for semi-hydrogenation of dehydroisophytol
(DIP), a C 20-alkynol, is reported. A series of unsupported mono-(Pd) and bimetallic (Pd-M) …

Continuous chemoselective methylation of functionalized amines and diols with supercritical methanol over solid acid and acid− base bifunctional catalysts

T Oku, Y Arita, H Tsuneki, T Ikariya - Journal of the American …, 2004 - ACS Publications
The selective N-methylation of bifunctionalized amines with supercritical methanol
(scCH3OH) promoted by the conventional solid acids (H-mordenite, β-zeolite, amorphous …