Salen complexes are widely employed in catalysis and biomedical science and chiral salen
complexes are among the most important catalysts for asymmetric synthesis. Their reduced …

In this paper, we describe our recent results with three families of Ti (IV) complexes,
elaborating on their cytotoxic activity, hydrolytic behavior, and the potential connection …

Alkane elimination reactions of amino-amino-bis (phenols) H 2 L 1-4, Salan H 2 L 5, and
methoxy-β-diimines HL 6, 7 with lanthanide tris (alkyl) s, Ln (CH2SiMe3) 3 (THF) 2 (Ln= Y …

A series of tetradentate amine (bisphenolate) ligands have been synthesized and
complexed to Ti (IV), Zr (IV), and Hf (IV) centers. Two distinct ligand sets have been …

We report the synthesis and characterization of several chiral salen-and salan-type ligands
and their vanadium complexes, which are derived from salicylaldehyde or salicylaldehyde …

Synthetic routes to aluminium ethyl complexes supported by chiral tetradentate
phenoxyamine (salan‐type) ligands [Al (OC6H2 (R‐6‐R‐4) CH2) 2 {CH3N (C6H10) NCH3} …

Stiffening of the catalyst backbone of salan-type catalyst 1via ring closure yields
indanosalan 3 and increases activity and molar mass capability by two orders of magnitude …

Chiral Salan ligands were found to wrap in a highly diastereoselective manner around
zirconium leading to C 2-symmetric complexes of predetermined chirality at the metal. These …

Bis (isopropoxo) Ti (IV) complexes of diamino bis (phenolato)“salan” ligands were prepared,
their hydrolysis in 1: 9 water/THF solutions was investigated, and their cytotoxicity toward …

Carefully design your ligand! A new family of highly cytotoxic TiIV complexes demonstrates
strong dependence of activity on the particular ligand employed, in which small structural …