Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …

Isolation of cyclic (alkyl) amino carbenes (cAACs) in 2005 has been a major achievement in
the field of stable carbenes due to their better electronic properties. cAACs and bicyclic …

Activation of inert molecules like CO2 is often mediated by cooperative chemistry between
two reactive sites within a catalytic assembly, the most common form of which is Lewis …

In order to isolate a monometallic Mg radical, the precursor (Am) MgI⋅(CAAC)(1) was
prepared (Am= tBuC (N‐DIPP) 2, DIPP= 2, 6‐diisopropylphenyl, CAAC= cyclic …

Electrophilic AlIII species have long dominated the aluminum reactivity towards arenes.
Recently, nucleophilic low‐valent AlI aluminyl anions have showcased oxidative additions …

The reactions of dipotassium 3, 4-dimethyl-2, 5-bis (trimethylsilyl)-germole dianion K2 [1]
with YCl3 and Cp* YCl2 (Cp*= cyclopentadienyl) in THF at room temperature afforded the …

Radicals of the lightest group 13 element, boron, are well established and observed in
numerous forms. In contrast to boron, radical chemistry involving the heavier group 13 …

The reaction of amidinatosilylene LSi (:) Cl [L= PhC (N t Bu) 2] with N-heterocyclic carbene
IAr [: C {N (Ar) CH} 2, where Ar= 2, 6-i Pr2C6H3] and NaOTf in tetrahydrofuran (THF) facilely …

The chemistry of cyclic (alkyl)(amino) carbene (CAAC) ligands is presented. Their electronic
structure is discussed and put into the context of conventional N-heterocyclic carbene (NHC) …

Abstract Die Radikale des leichtesten Elements der Gruppe 13, Bor, sind gut bekannt und
werden in zahlreichen Formen beobachtet. Im Gegensatz zu Bor ist die Radikalchemie mit …