Visible-to-NIR-light activated release: from small molecules to nanomaterials

R Weinstain, T Slanina, D Kand, P Klan - Chemical reviews, 2020 - ACS Publications
Photoactivatable (alternatively, photoremovable, photoreleasable, or photocleavable)
protecting groups (PPGs), also known as caged or photocaged compounds, are used to …

PhotoCORMs: CO release moves into the visible

MA Wright, JA Wright - Dalton Transactions, 2016 - pubs.rsc.org
The potential of carbon monoxide to act as a therapeutic agent is now well-established.
Controlled delivery of CO is best achieved using 'CORMs': molecules which release known …

Novel oxidovanadium complexes with redox-active r-mian and r-bian ligands: synthesis, structure, redox and catalytic properties

AN Lukoyanov, IS Fomenko, MI Gongola, LS Shul'pina… - Molecules, 2021 - mdpi.com
A new monoiminoacenaphthenone 3, 5-(CF3) 2C6H3-mian (complex 2) was synthesized
and further exploited, along with the already known monoiminoacenaphthenone dpp-mian …

A luminescent manganese PhotoCORM for CO delivery to cellular targets under the control of visible light

J Jimenez, I Chakraborty, A Dominguez… - Inorganic …, 2018 - ACS Publications
A photoactive manganese carbonyl complex derived from dansylimidazole (Imdansyl),
namely,[Mn (Imdansyl)(CO) 3 (phen)](CF3SO3)(1), has been synthesized and structurally …

Red-light activated photoCORMs of Mn (I) species bearing electron deficient 2, 2′-azopyridines

E Kottelat, A Ruggi, F Zobi - Dalton Transactions, 2016 - pubs.rsc.org
The realization of CO releasing molecules triggered by light (photoCORMs) within the
phototherapeutic window (λ> 600 nm) constitutes an important goal for potential therapeutic …

Bioinorganic systems responsive to the diatomic gases O2, NO, and CO: From biological sensors to therapy

LG de Franca Lopes, FSG Júnior, AKM Holanda… - Coordination Chemistry …, 2021 - Elsevier
The diatomic molecules, O 2, NO and CO, have had a myriad of roles in biology. Due to this,
nature has developed many sensing proteins to perceive and respond to changes in the …

Synthesis and Catalysis of Redox‐Active Bis (imino) acenaphthene (BIAN) Iron Complexes

M Villa, D Miesel, A Hildebrandt, F Ragaini… - …, 2017 - Wiley Online Library
Reactions of various substituted bis (imino) acenaphthenes (R‐BIANs) with FeCl2 (thf) 1.5
afforded the tetrahedral complexes (R‐BIAN) FeCl2 (2) from bulky α‐diimines and the …

Visible-light-activated photoCORMs: rational design of CO-releasing organic molecules absorbing in the tissue-transparent window

T Slanina, P Šebej - Photochemical & Photobiological Sciences, 2018 - pubs.rsc.org
To date, most known molecules that release carbon monoxide by the action of light are
based on carbonyl complexes of metals. However, they suffer from several disadvantages …

Ultrafast Spectroscopy of [Mn(CO)3] Complexes: Tuning the Kinetics of Light-Driven CO Release and Solvent Binding

WC Henke, CJ Otolski, WNG Moore, CG Elles… - Inorganic …, 2020 - ACS Publications
Manganese tricarbonyl complexes are promising catalysts for CO2 reduction, but complexes
in this family are often photosensitive and decompose rapidly upon exposure to visible light …

Chemical and Electrochemical Reductions of Monoiminoacenaphthenes

VV Khrizanforova, RR Fayzullin… - International Journal of …, 2023 - mdpi.com
Redox properties of monoiminoacenaphthenes (MIANs) were studied using various
electrochemical techniques. The potential values obtained were used for calculating the …