Field-cycling NMR relaxometry of viscous liquids and polymers

D Kruk, A Herrmann, EA Rössler - Progress in nuclear magnetic resonance …, 2012 - Elsevier
Field-cycling (FC) NMR relaxometry is a very important source of information on dynamical
and structural features of molecules. It is especially well established for liquids and …

Simulating the flow of entangled polymers

Y Masubuchi - Annual review of chemical and biomolecular …, 2014 - annualreviews.org
To optimize automation for polymer processing, attempts have been made to simulate the
flow of entangled polymers. In industry, fluid dynamics simulations with phenomenological …

Self-similar conformations and dynamics in entangled melts and solutions of nonconcatenated ring polymers

T Ge, S Panyukov, M Rubinstein - Macromolecules, 2016 - ACS Publications
A scaling model of self-similar conformations and dynamics of nonconcatenated entangled
ring polymers is developed. Topological constraints force these ring polymers into compact …

Stress relaxation in symmetric ring-linear polymer blends at low ring fractions

D Parisi, J Ahn, T Chang, D Vlassopoulos… - …, 2020 - ACS Publications
We combine linear viscoelastic measurements and modeling in order to explore the
dynamics of blends of the same-molecular-weight ring and linear polymers in the regime of …

Dynamics of model ionomer melts of various architectures

LM Hall, MJ Stevens, AL Frischknecht - Macromolecules, 2012 - ACS Publications
Ion-containing polymers have potential as single-ion conducting battery electrolyte
materials. Their conductivity is often too low for such applications due to the low dielectric …

Time-domain NMR observation of entangled polymer dynamics: Universal behavior of flexible homopolymers and applicability of the tube model

F Vaca Chávez, K Saalwächter - Macromolecules, 2011 - ACS Publications
Using a benchtop NMR spectrometer, we performed proton multiple-quantum NMR
experiments to study the dynamics of well-entangled linear poly (butadiene), poly …

Dynamical entanglement and cooperative dynamics in entangled solutions of ring and linear polymers

D Michieletto, T Sakaue - ACS Macro Letters, 2020 - ACS Publications
Understanding how entanglements affect the behavior of polymeric complex fluids is an
open challenge in many fields. To elucidate the nature and consequence of entanglements …

Stress relaxation in entangled polymer melts

JX Hou, C Svaneborg, R Everaers, GS Grest - Physical review letters, 2010 - APS
We present an extensive set of simulation results for the stress relaxation in equilibrium and
step-strained bead-spring polymer melts. The data allow us to explore the chain dynamics …

Microscopic definition of polymer entanglements

AE Likhtman, M Ponmurugan - Macromolecules, 2014 - ACS Publications
The dynamics of polymer melts and concentrated solutions is notoriously slow due to the fact
that long polymer chains cannot cross each other and therefore find themselves entangled …

Chain entanglements in polyethylene melts. Why is it studied again?

VM Litvinov, ME Ries, TW Baughman, A Henke… - …, 2013 - ACS Publications
The aim of this study is to revisit the characterization of entanglement density in polyethylene
melts by studying a series of well-defined, high molecular weight polyethylene materials via …