Horner–Wadsworth–Emmons reaction as an excellent tool in the synthesis of fluoro-containing biologically important compounds

M Bilska-Markowska, M Kaźmierczak - Organic & Biomolecular …, 2023 - pubs.rsc.org
Selective introduction of a double bond motif into a multifunctional organic compound is
always a big challenge. The Horner–Wadsworth–Emmons reaction is one of the most …

Palladium-catalyzed coupling reactions in flavonoids: A retrospective of recent synthetic approaches

ITL Ramos, RJM Silva, TMS Silva… - Synthetic …, 2021 - Taylor & Francis
Palladium-catalyzed coupling reactions are among the most important for forming carbon–
carbon bonds in organic synthesis. These reactions are frequently employed in the …

Copper and Palladium Cocatalyzed Defluorinative Coupling of gem-Difluoroalkenes and Acyl Chloride

X Liu, J Wu, C Zhang - Organic Letters, 2023 - ACS Publications
A novel copper and palladium cocatalyzed defluorinative coupling of gem-difluoroalkenes
and acyl chlorides has been developed. It is a practical method to prepare α …

α‐Substituted Chalcones: A Key Review

NM Al‐Rifai, MS Mubarak - ChemistrySelect, 2021 - Wiley Online Library
Chalcones are attractive chemical motifs with various biological activities. Aryl substituted
chalcones have been extensively studied and reviewed through the years. However, α …

Fabrication of covalently functionalized mesoporous silica core–shell magnetite nanoparticles with palladium (II) acetylacetonate: application as a magnetically …

A Hajipour, G Azizi - Applied Organometallic Chemistry, 2015 - Wiley Online Library
We report the preparation of supported palladium (II) acetylacetonate, Pd (acac) 2,
coordinated by pendant acac groups, by reacting palladium acetate with acac …

Synthesis of α‐Fluoroenones by Elimination of α‐Chloro‐α‐fluoroketones

A Naruse, K Kitahara, S Iwasa… - Asian Journal of …, 2019 - Wiley Online Library
A new synthetic route to α‐fluoroenones was developed. Decarboxylative chlorination of α‐
fluoro‐β‐oxocarboxylic acids afforded α‐chloro‐α‐fluoroketones, and subsequent base …

Building block synthesis of predominantly (E) symmetrical and unsymmetrical 1, 2-difluorostilbenes from 1, 2-dibromo-1, 2-difluoroethene

S Eddarir, M Kajjout, C Rolando - Tetrahedron, 2013 - Elsevier
An efficient synthesis of predominantly (E) symmetrical or unsymmetrical 1, 2-
difluorostilbenes based on the Suzuki–Miyaura palladium-catalyzed cross-coupling reaction …