In this tutorial review, recent advances in the synthesis of cyclopropane-containing natural
products are discussed, highlighting the application of novel synthetic methodologies and …

The synthesis of naturally occurring substances has been a central part of synthetic organic
chemistry since the late 19th century. Looking back on 150 years of history, the primary …

Vilmoraconitine belongs to one of the most complex skeleton types in the C19-diterpenoid
alkaloids, which architecturally features an unprecedented heptacyclic core possessing a …

Platensilin, platensimycin, and platencin are potent inhibitors of β-ketoacyl–acyl carrier
protein synthase (FabF) in the bacterial and mammalian fatty acid synthesis system …

We present a bioinspired late-stage C–H oxidation of the ent-trachylobane natural product
mitrephorone B to mitrephorone A. The realization of this unprecedented transformation was …

The first synthesis of (−)-mitrephorone A is disclosed along with discussion and study of
synthetic strategies. The natural product includes a highly congested hexacyclic ent …

Herein, we present our studies to construct seven ent‐trachylobane diterpenoids by
employing a bioinspired two‐phase synthetic strategy. The first phase provided …

The coupling-isomerization reaction is an unusual outcome of the Sonogashira coupling of
propargyl alcohols, N-tosylamines, or ethers with preferentially electron-deficient (hetero) …

The crispatenes and SNF4435 C&D are complex polypropionate derived natural products.
The core structures of these compounds along with a complex unnatural structure can be …

Abstract Diastereotopic group selection in 1, 4-cyclohexadienes is a useful approach to
synthesize rather complex compounds in a single operation. The stereoinduction occurs via …