Recent developments in alkene hydrosilylation utilizing manganese catalysts

N Katayama, Y Obora - Tetrahedron Letters, 2023 - Elsevier
Hydrosilylation of alkenes is an important process in the synthesis of organosilicon
compounds in which an Si–H species is added across a carbon–carbon double bond (C …

(NHC) Ni (0)-catalyzed branched-selective alkene hydrosilylation with secondary and tertiary silanes

AS Chang, KE Kawamura, HS Henness… - ACS …, 2022 - ACS Publications
Hydrosilylation is a valuable approach for the construction of organosilanes, which are
precursors to silicone materials that are widely incorporated in our everyday lives. The …

Co‐Catalyzed Hydrosilylation of Ketones under Base‐Free Conditions: A Convenient Route to Silyl Ethers or Secondary Alcohols

H Stachowiak‐Dłużyńska, G Hreczycho - ChemCatChem, 2023 - Wiley Online Library
A cobalt‐catalyzed addition of hydrosilanes to unsaturated carbon‐oxygen bonds has been
developed, relying on complexes featuring easily accessible and inexpensive PNP‐type …

Cobalt Complexes Supported by Phosphinoquinoline Ligands for the Catalyzed Hydrosilylation of Carbonyl Compounds

P Schiltz, N Casaretto, A Auffrant… - Chemistry–A European …, 2022 - Wiley Online Library
P, N phosphinoquinoline based ligands differing by the nature of the phosphorus substituent
(iPr, Ph) were employed to synthesize a series of cobalt (II) complexes ([LCoBr2],[L2CoBr] …

State of the Art in Rhodium-and Iridium-Catalyzed Hydrosilylation Reactions

M Iglesias, FJ Fernández-Alvarez, LA Oro - Perspectives of Hydrosilylation …, 2023 - Springer
This chapter reviews the state of the art of rhodium-and iridium-catalyzed hydrosilylation
reactions, demonstrating the utility of rhodium and iridium catalysts for organic synthesis …

The effect of Schiff base ligands on the structure and catalytic activity of cobalt complexes in hydrosilylation of olefins

A Bocian, M Skrodzki, M Kubicki, A Gorczyński… - Applied Catalysis A …, 2020 - Elsevier
Environmental and economic aspects render the search for new nonprecious metal
hydrosilylation catalysts an up-to-date challenge. Cobalt stands as an interesting alternative …

Cobalt bis (2‐ethylhexanoate) and terpyridine derivatives as catalysts for the hydrosilylation of olefins

Z Dai, Z Yu, Y Bai, J Li, J Peng - Applied Organometallic …, 2021 - Wiley Online Library
A simple method for the hydrosilylation of olefins by using air‐stable cobalt catalysts is
developed. The catalyst system is composed of simple, cheap, and readily available cobalt …

Reactions of Nickel (0)–Olefin Pincer Complexes with Terminal Alkynes: Cooperative C–H Bond Activation and Alkyne Coupling

MLG Sansores-Paredes, TTT Nguyen, M Lutz… - …, 2023 - ACS Publications
Metal–ligand cooperation can facilitate the activation of chemical bonds, opening reaction
pathways of interest for catalyst development. In this context, olefins occupying the central …

Imidazolinium‐functionalized Complexes of Cobalt and Iron as Catalysts for Hydrosilylation Reactions

L Chen, Y Huo, M Tai, X Wang, X Gui, Y Tu… - …, 2022 - Wiley Online Library
The hydrosilylation addition reaction is one of the most important methods for the synthesis
of silicone compounds, in which the catalyst plays an extremely important role. Currently, the …

Highly active cobalt complex catalysts used for alkene hydrosilylation

Y Liu, J Li, Y Bai, J Peng - Applied Organometallic Chemistry, 2021 - Wiley Online Library
A series of nitrogen phosphine ligands were synthesized, and the hydrosilylation reaction of
alkenes catalyzed using MCl2 in the presence of these ligands was investigated. FeCl2/1 …