C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

Readily accessible and shelf-stable 1, 2, 3-triazole and its analogues such as pyridotriazole,
triazoloindole, benzotriazole, and thiadiazole exist in equilibrium with their ring-opened …

Metal-stabilized carbenes derived from diazo compounds have become broadly useful
reactive intermediates for organic synthesis. This tutorial review will describe the recent …

An unprecedented direct C–H bond functionalization of unprotected phenols with α-aryl α-
diazoacetates and diazooxindoles was developed. A tris (2, 4-di-tert-butylphenyl) phosphite …

In recent years, α‐imino rhodium carbene complexes derived by ring‐opening of N‐sulfonyl‐
1, 2, 3‐triazoles have attracted much attention from organic chemists. Many transformations …

The high demand for new and efficient routes toward synthesis of nitrogen-containing
heterocyclic scaffolds has inspired organic chemists to discover several methodologies over …

Suitably substituted electron-deficient 1, 2, 3-triazoles exist in equilibrium with their ring-
opened α-diazoimine tautomers. This phenomenon was used to facilitate the generation of …

A highly efficient and practical method for incorporation of the arylmethylpyridyl moiety into
diverse molecules has been developed. This method features the transition metal-free light …

We report a method that ensures the selective alkylation of benzamides and aromatic
ketones at the para-position via cooperative nickel/aluminum catalysis. Using a bulky …

Herein, we conceptualized a transient mediator approach that has the capability of para-
selective CH functionalization of monosubstituted aromatics. This approach is enabled by in …